60815-18-1

Basic information

• Product Name: (3-METHOXYBENZYL)PHOSPHONIC ACID DIETHYL ESTER
• Synonyms: 3-(DIETHYLPHOSPHONOMETHYL)ANISOLE;(3-METHOXYBENZYL)PHOSPHONIC ACID DIETHYL ESTER;Diethyl 3-Methoxybenzyl phosphonate, 98 %;m-Methoxybenzylphosphonic acid diethyl ester;Diethyl 3-methoxyben;3-(Diethylphosphonomethyl)anisole (3-Methoxybenzyl)phosphonic Acid Diethyl Ester;diethyl [(3-Methoxyphenyl)Methyl]phosphonate;DIETHYL (3-METHOXYBENZYL)PHOSPHONATE
• CAS NO: 60815-18-1
• Molecular Formula: C₁₂H₁₉O₄P
• Molecular Weight: 258.25
• Mol File: 60815-18-1.mol
• Article Data: 18

Chemical Properties

• Boiling Point: 135 °C / 0.5mmHg
• Flash Point: 187.256 °C
• Appearance: /
• Density: 1.13
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.5020-1.5060
• Storage Temp.: Hygroscopic, Refrigerator, under inert atmosphere
• Solubility: Chloroform (Sparingly)
• Stability: Moisture Sensitive
• CAS DataBase Reference: (3-METHOXYBENZYL)PHOSPHONIC ACID DIETHYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: (3-METHOXYBENZYL)PHOSPHONIC ACID DIETHYL ESTER(60815-18-1)
• EPA Substance Registry System: (3-METHOXYBENZYL)PHOSPHONIC ACID DIETHYL ESTER(60815-18-1)

Safety Data

• Hazardous Substances Data: 60815-18-1(Hazardous Substances Data)

Usage

General Description

(3-Methoxybenzyl)phosphonic acid diethyl ester is a chemical compound with the molecular formula C12H17O4P. It is an ester derivative of (3-Methoxybenzyl)phosphonic acid and is used in various chemical and pharmaceutical applications. (3-Methoxybenzyl)phosphonic acid diethyl ester is an organophosphorus compound, meaning it contains a phosphorus atom bonded to a carbon atom. It is commonly used as a phosphonate ester which has potential use as corrosion inhibitors, flame retardants, and as stabilizers for industrial processes. Additionally, it can also be used as a reagent in organic synthesis and in the production of various pharmaceuticals.

InChI:InChI=1/C12H19O4P/c1-4-15-17(13,16-5-2)10-11-7-6-8-12(9-11)14-3/h6-9H,4-5,10H2,1-3H3

Upstream product

• 67-56-1 methanol 
• 134891-99-9 diethyl <(3-oxo-1-cyclohexen-1-yl)methyl>phosphonate 
• 6971-51-3 3-methoxybenzyl alcohol 
• 122-52-1 triethyl phosphite 
• 78-40-0 triethyl phosphate 
• 874-98-6 1-bromomethyl-3-methoxybenzene 
• 824-98-6 m-methoxybenzyl chloride 

Downstream Products

• 364046-33-3 (diethoxy-phosphoryl)-(3-methoxy-phenyl)-acetic acid 
• 1030917-88-4 ethyl 4-[(Z)-2-(3-methoxyphenyl)ethenyl]-1-methyl-1H-pyrrole-2-carboxylate 
• 1030917-87-3 ethyl 4-[(E)-2-(3-methoxyphenyl)ethenyl]-1-methyl-1H-pyrrole-2-carboxylate 
• 1072930-86-9 1-[benzyloxy]-2-[2-(3-methoxyphenyl)ethenyl]benzene 
• 38693-96-8 4-Fluor-3'-methoxy-trans-stilben 
• 31338-30-4 1-(4-pyridyl)-2-(3-methoxyphenyl)ethene 
• 167145-13-3 2-[2-(3-methoxyphenyl)ethyl]phenol 
• 143212-74-2 1-(2-hydroxyphenyl)-2-(3-methoxyphenyl)ethylene 

Relevant articles and documents

A new insight into the push-pull effect of substituents via the stilbene-like model compounds

In this paper, authors report on 1-pyridyl-2-arylethenes, 1-furyl-2-arylethylenes, 1,2-diphenylpropylenes and substituted cinnamyl anilines as stilbene-like model compounds to investigate the factors dominating the push-pull effect of substituents via usi

Determination and application of the excited-state substituent constants of pyridyl and substituted phenyl groups

Thirty six 1-pyridyl-2-arylethenes XCH=CHArY (abbreviated XAEY) were synthesized, in which, X is 2-pyridyl, 3-pyridyl and 4-pyridyl and Y is OMe, Me, H, Br, Cl, F, CF3, and CN. Their ultraviolet absorption spectra were measured in anhydrous ethanol, and their wavelengths of absorption maximum λmax were recorded. Also, the 234 λmax values of 1-substituted phenyl-2-arylethylene compounds (XAEY, where X is substituted phenyl) were collected. The excited-state substituent constants (Formula presented.) of three pyridyl groups and 23 substituted phenyl groups (total of 26) were obtained by means of curve-fitting method. Taking the λmax values of 358 samples of bi-arylethene derivatives as a data set and 126 samples of bi-aryl Schiff bases (including nine compounds synthesized by this work) as another data set, quantitative correlation analyses were performed by employing the obtained (Formula presented.) as a parameter, and good results were obtained for the two data sets. The reliability of the obtained (Formula presented.) values was verified. The results of this paper can provide excited-state substituent constants for the study and application of optical properties of conjugated organic compounds containing aryl groups.

Synthetic method for alkyl group phosphorous acid diester compounds or alkyl group phosphinic acid ester compounds

The invention discloses a synthetic method for alkyl group phosphorous acid diester compounds or alkyl group phosphinic acid ester compounds. According to the synthetic method, alcohols which are cheap, easy to get, wide in source, stable and low in toxicity serve as alkylating reagents, iodine salt which is cheap and easy to get serves as catalysts, no solvent is needed, and the alkyl group phosphorous acid diester compounds can be selectively directly obtained after a reaction. The reaction method is simple, the condition is mild, no organic solvent is needed and operation is simple. According to the method, the requirements for reaction conditions are low, various types of alcohols such as a benzyl group type, an allyl type and a fat type can be utilized as the alkylate reagents to implement the synthesis of different types of substituted alkyl group phosphorous acid diester, and the method can be further expanded to the synthesis of the alkyl group phosphinic acid ester compounds through the reaction between the substituted phosphonous acid diester and the alcohols.