61219-95-2

Basic information

• Product Name: N-Allyl-2,2-dichloro-N-[3-(trifluoromethyl)phenyl]acetamide
• Synonyms: N-ALLYL-2,2-DICHLORO-N-[3-(TRIFLUOROMETHYL)PHENYL]ACETAMIDE;LABOTEST-BB LT00795814;2,2-dichloro-n-2-propenyl-n-[3-(trifluoromethyl)phenyl]acetamide;AMIDE C2;ACETIC ACID AMIDE;Aeetamide;Einecs 262-669-7
• CAS NO: 61219-95-2
• Molecular Formula: C₁₂H₁₀Cl₂F₃NO
• Molecular Weight: 312.12
• EINECS: 200-473-5
• Mol File: 61219-95-2.mol
• Article Data: 1

Chemical Properties

• Melting Point: 78-80 °C(lit.)
• Boiling Point: 221 °C(lit.)
• Flash Point: 152.9 °C
• Appearance: /
• Density: 1.382 g/cm³
• Vapor Pressure: 1 mm Hg ( 65 °C)
• Refractive Index: 1.521
• Storage Temp.: 2-8°C
• Solubility: H2O: 0.5 g/mL, Hazen ≤50
• PKA: -1.24±0.50(Predicted)
• CAS DataBase Reference: N-Allyl-2,2-dichloro-N-[3-(trifluoromethyl)phenyl]acetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-Allyl-2,2-dichloro-N-[3-(trifluoromethyl)phenyl]acetamide(61219-95-2)
• EPA Substance Registry System: N-Allyl-2,2-dichloro-N-[3-(trifluoromethyl)phenyl]acetamide(61219-95-2)

Safety Data

• Hazard Codes: Xn
• Statements: 40
• Safety Statements: 36/37
• RIDADR: UN 3077 9/PG 3
• WGK Germany: 1
• RTECS: AB4025000
• F: 3
• Hazardous Substances Data: 61219-95-2(Hazardous Substances Data)

Usage

Uses

N-Allyl-2,2-dichloro-N-[3-(trifluoromethyl)phenyl]acetamide is related to Flurochloridon(F599033), which can be used in herbicidal composition to control weed in crop fields.

InChI:InChI=1/C12H10Cl2F3NO/c1-2-6-18(11(19)10(13)14)9-5-3-4-8(7-9)12(15,16)17/h2-5,7,10H,1,6H2

Upstream product

• 2837-61-8 dichloro-acetic acid-(3-trifluoromethyl-anilide) 
• 107-05-1 3-chloroprop-1-ene 

Downstream Products

• 61213-60-3 trans-Fluorochloridone 
• 61213-59-0 cis-Fluorochloridone 
• 61213-25-0 fluorochloridone 

Relevant articles and documents

Synthesis method for improving purity of fluorochloridone

The invention discloses a synthesis method for improving the purity of fluorochloridone, and belongs to the technical field of pesticide intermediates. The synthesis method comprises the following steps: S1, taking a compound shown as a formula (III) and allyl chloride as raw materials, taking an alkaline solution or a salt solution as a solvent, carrying out catalytic reaction at 20-25 DEG C under the action of a phase transfer catalyst, and treating after the reaction is finished to obtain a compound shown as a formula (II); S2, taking the compound as shown in the formula (II) as a raw material, taking anhydrous 1, 2-dichloroethane as a solvent, and carrying out reflux reaction at 80-100 DEG C for 4-6 hours under the combined catalytic action of cuprous chloride and 2, 2-dipyridyl, so as to prepare a mixture containing fluorochloridone; and S3, purifying the fluorochloridone. During purification, an extraction solvent is adopted, large-polarity by-products can be removed to a great extent, and residues are simply stirred and washed by n-hexane, so that a fluorochloridone raw material medicine with the purity of more than 95% can be obtained.