613-56-9

Basic information

• Product Name: 2,2'-DINAPHTHYL KETONE
• Synonyms: 2,2'-DINAPHTHYL KETONE;dinaphthalen-2-yl-methanone
• CAS NO: 613-56-9
• Molecular Formula: C₂₁H₁₄O
• Molecular Weight: 282.34
• Mol File: 613-56-9.mol
• Article Data: 2

Chemical Properties

• Melting Point: 164.5 °C
• Boiling Point: 485.692°C at 760 mmHg
• Flash Point: 215.983°C
• Appearance: /
• Density: 1.197g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.706
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 2,2'-DINAPHTHYL KETONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-DINAPHTHYL KETONE(613-56-9)
• EPA Substance Registry System: 2,2'-DINAPHTHYL KETONE(613-56-9)

Safety Data

• Hazardous Substances Data: 613-56-9(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 45, p. 3840, 1980 DOI: 10.1021/jo01307a022

InChI:InChI=1/C21H14O/c22-21(19-11-9-15-5-1-3-7-17(15)13-19)20-12-10-16-6-2-4-8-18(16)14-20/h1-14H

Upstream product

• 19226-36-9 3-phenyl-5H-1,4,2-dioxazol-5-one 
• 4541-70-2 2-naphthyllithium 
• 21473-01-8 2-naphthalenylmagnesium bromide 
• 2243-83-6 2-naphthaloyl chloride 

Downstream Products

• 91-20-3 naphthalene 
• 93-09-4 naphthalene-2-carboxylate 
• 76385-35-8 (2-allylphenyl)(phenyl)methanone 
• 612-78-2 2,2'-binaphthalene 
• 4809-95-4 bis(β-naphthyl)methanol 
• 1426339-73-2 tri(naphthalen-2-yl)phenylethene 
• 225367-72-6 C₂₈H₂₂N₂O₂S 
• 216070-60-9 tri(naphthalene-2-yl)methanol 

Relevant articles and documents

Co(III)-Catalyzed Synthesis of Quinazolines via C-H Activation of N-Sulfinylimines and Benzimidates

C-H activation of arenes has been established as an important strategy for heterocycle synthesis via annulations between arenes and unsaturated coupling partners. However, nitriles failed to act as such a coupling partner. Dioxazolones have been employed as a synthon of nitriles, and subsequent coupling with arenes such as N-sulfinylimines and benzimidates bearing a functionalizable directing group provided facile access to two classes of quinazolines under Co(III)-catalysis.