613241-83-1

Basic information

• Product Name: 1-methyl-1-(4-methyl-3-cyclohexenyl)ethyl hydroperoxide
• Synonyms: 1-methyl-1-(4-methyl-3-cyclohexenyl)ethyl hydroperoxide
• CAS NO: 613241-83-1
• Molecular Weight: 170.252
• Mol File: 613241-83-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-methyl-1-(4-methyl-3-cyclohexenyl)ethyl hydroperoxide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-1-(4-methyl-3-cyclohexenyl)ethyl hydroperoxide(613241-83-1)
• EPA Substance Registry System: 1-methyl-1-(4-methyl-3-cyclohexenyl)ethyl hydroperoxide(613241-83-1)

Safety Data

• Hazardous Substances Data: 613241-83-1(Hazardous Substances Data)

Upstream product

• 776-76-1 methyldiphenylsilane 
• 5989-54-8 (-)-(S)-limonene 

Downstream Products

• 10482-56-1 (-)-(S)-α-terpineol 

Relevant articles and documents

Co-catalyzed autoxidation of alkene in the presence of silane. The effect of the structure of silanes on the efficiency of the reaction and on the product distribution

A systematic investigation of the structural effect of silanes on the Co-catalyzed reductive oxygenation of alkene in the presence of silane (Mukaiyama-Isayama reaction) showed that the efficiency of the reaction decreases with the increase of the steric bulk of the silanes. A similar trend was observed for the metal-exchange reaction between Co(III)-alkylperoxo complex and silane, too. The peroxidation of (S)-limonene, followed by deprotection of the derived silyl peroxides, provides a mixture of the corresponding monocyclic hydroperoxide 24 and the bicyclic one 25, the ratio being a marked function of the steric bulk of silanes.