61452-49-1Relevant articles and documents
Sml2-promoted reformatsky-type reaction and acylation of alkyl 1-chlorocyclopropanecarboxylates
Nagano, Takao,Motoyoshiya, Jiro,Kakehi, Akikazu,Nishii, Yoshinori
supporting information; experimental part, p. 5453 - 5456 (2009/06/28)
(Chemical Equation Presented) In the presence of HMPA in THF, highly stereoselective Sml2-promoted substitutions of alkyl 1-chlorocyclopropanecarboxylates 1 using various ketones, aldehydes (Reformatsky-type reaction), and acyl chlorides (acyla
Calixarenes as ligands for transition-metal catalysts: A bis(calix[4]arene-11,23-dicarboxylato) dirhodium complex
Seitz, Juergen,Maas, Gerhard
, p. 338 - 339 (2007/10/03)
A novel dirhodium tetracarboxylate complex is described in which two calix[4]arene macrocycles, bridged at the upper rim by a Rh-Rh unit, serve as ligands and whose solid-state structure shows an unusual coordination of a toluene molecule in the axial pos
Transition-Metal-Catalyzed Reactions of Diazo Compounds. 1. Cyclopropanation of Double Bonds
Anciaux, Andre J.,Hubert, Andre J.,Noels, Alfred F.,Petiniot, N.,Teyssie, Philippe
, p. 695 - 702 (2007/10/02)
Rhodium(II) and palladium(II) carboxylates are efficient catalysts for the cyclopropanation of olefins by diazo esters.Intramolecular competitions within diolefins and intermolecular competitions between pairs of monoolefins showed quite different cyclopr