61836-03-1

Basic information

• Product Name: Benzene, [(1-methyl-3-phenylpropyl)thio]-
• CAS NO: 61836-03-1
• Molecular Formula: C16H18S
• Molecular Weight: 242.385
• Mol File: 61836-03-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-methyl-3-phenylpropyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-methyl-3-phenylpropyl)thio]-(61836-03-1)
• EPA Substance Registry System: Benzene, [(1-methyl-3-phenylpropyl)thio]-(61836-03-1)

Safety Data

• Hazardous Substances Data: 61836-03-1(Hazardous Substances Data)

Upstream product

• 59456-20-1 (rac)-(3-iodobutyl)benzeze 
• 108-98-5 thiophenol 
• 2344-70-9 1-phenyl-3-butanol 
• 930-69-8 sodium thiophenolate 
• 4551-15-9 phenylthiotrimethylsilane 
• 141809-67-8 1-methyl-3-phenylpropyl trimethylsilyl ether 
• 143097-80-7 2-bromo-4-phenylbutane 
• 10415-88-0 4-phenylbut-2-yl acetate 
• 2550-26-7 4-Phenyl-2-butanone 
• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 201230-82-2 carbon monoxide 
• 66080-31-7 4,4,5,5-tetramethyl-2-(3-phenyl-1-phenylsulfanyl-propyl)-[1,3,2]dioxaborolane 
• 74-88-4 methyl iodide 

Downstream Products

• 768-56-9 4-Phenylbut-1-ene 
• 959929-03-4 (rac)-[(4-phenylbutan-2-yl)sulfonyl]benzene 
• 79399-24-9 (rac)-[(2-methyl-4-phenylbutan-2-yl)sulfonyl]-benzene 
• 4489-84-3 3-methyl-1-phenylbut-2-ene 
• 6683-51-8 2-methyl-4-phenyl-1-butene 

Relevant articles and documents

Two-Step Protocol for Iodotrimethylsilane-Mediated Deoxy-Functionalization of Alcohols

We have developed a two-step protocol for iodotrimethylsilane-mediated deoxy-functionalization of primary and secondary alcohols to afford products containing a C?N, C?S, or C?O bond. In the first step the alcohol undergoes iodination with iodotrimethylsilane, and in the second, the iodine atom is replaced by a N, S, or O nucleophile. Compared with traditional Mitsunobu reaction, non-acidic pre-nucleophiles can be used, and the reaction proceeds with retention of configuration. This operationally simple, highly efficient protocol can be used for some natural products and small-molecule drugs containing hydroxy-group.

Synthesis of thioethers by ini3-catalyzed substitution of siloxy group using thiosilanes

The substitution of a siloxy group using thiosilanes smoothly occurred in the presence of InI3 catalyst to yield the corresponding thioethers. InI3was a specifically effective catalyst in this reaction system, while other typical Lew

Synthesis of a wide range of thioethers by indium triiodide catalyzed direct coupling between alkyl acetates and thiosilanes

An indium triiodide-catalyzed substitution of the acetoxy group in alkyl acetates with thiosilanes provides access to a variety of thioethers. The method is efficient for a wide scope of acetates such as primary alkyl, secondary alkyl, tertiary alkyl, allylic, benzylic, and propargylic acetates.