621-58-9

Basic information

• Product Name: Phenol,5-ethenyl-2-methoxy-
• CAS NO: 621-58-9
• Molecular Weight: 150.177
• Mol File: 621-58-9.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Phenol,5-ethenyl-2-methoxy- (CAS DataBase Reference)
• NIST Chemistry Reference: Phenol,5-ethenyl-2-methoxy- (621-58-9)
• EPA Substance Registry System: Phenol,5-ethenyl-2-methoxy- (621-58-9)

Safety Data

• Hazardous Substances Data: 621-58-9(Hazardous Substances Data)

Upstream product

• 621-59-0 isovanillin 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 831222-65-2 tert-butyl-(2-methoxy-5-vinylphenoxy)dimethylsilane 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 91-66-7 N,N-diethylaniline 
• 121-69-7 N,N-dimethyl-aniline 
• 313525-17-6 (4,5-dimethoxy-3-oxo-phthalan-1-yl)-acetic acid 

Downstream Products

• 50602-41-0 3-hydroxy-4-methoxyphenethyl alcohol 
• 68360-39-4 2-(3-benzyloxy-4-methoxyphenyl)ethylene 
• 1021172-43-9 C₂₂H₂₄O₃ 
• 1021172-45-1 C₂₀H₂₁BrO₃ 
• 1021172-38-2 C₂₂H₂₄O₃ 
• 1449510-35-3 (E)-4'-fluoro-4-methoxy-3,3',5'-trihydroxystilbene 
• 500-65-2 rhapontigenin 
• 1394048-05-5 (E)-3-hydroxy-2',4,5'-trimethoxystilbene 
• 1394048-04-4 (E)-4'-fluoro-3-hydroxy-3',4,5'-trimethoxystilbene 
• 1354834-33-5 (E)-1-(3-bromo-4-(methoxymethoxy)phenyl)-7-(3-hydroxy-4-methoxyphenyl)hept-6-en-3-one 
• 1354834-20-0 (E)-1-(3-bromo-4-methoxyphenyl)-7-(3-hydroxy-4-methoxyphenyl)hept-6-en-3-one 
• 108957-73-9 NSC₃₈₁₈₆₄ 
• 1335242-41-5 (E)-3-hydroxy-2',4,4'-trimethoxystilbene 
• 1335242-40-4 (E)-4-methoxy-2',3,5'-trihydroxystilbene 

Relevant articles and documents

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Regioselective enzymatic β-carboxylation of para-hydroxy-styrene derivatives catalyzed by phenolic acid decarboxylases

Abstract We report on a 'green' method for the utilization of carbon dioxide as C1 unit for the regioselective synthesis of (E)-cinnamic acids via regioselective enzymatic carboxylation of para-hydroxystyrenes. Phenolic acid decarboxylases from bacterial sources catalyzed the β-carboxylation of para-hydroxystyrene derivatives with excellent regio- and (E/Z)-stereoselectivity by exclusively acting at the β-carbon atom of the C=C side chain to furnish the corresponding (E)-cinnamic acid derivatives in up to 40% conversion at the expense of bicarbonate as carbon dioxide source. Studies on the substrate scope of this strategy are presented and a catalytic mechanism is proposed based on molecular modelling studies supported by mutagenesis of amino acid residues in the active site.