62337-90-0

Basic information

• Product Name: tert-Butylcyclohexylphosphine
• Synonyms: tert-Butylcyclohexylphosphine
• CAS NO: 62337-90-0
• Molecular Formula: C₁₀H₂₁P
• Molecular Weight: 0
• Mol File: 62337-90-0.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: tert-Butylcyclohexylphosphine(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butylcyclohexylphosphine(62337-90-0)
• EPA Substance Registry System: tert-Butylcyclohexylphosphine(62337-90-0)

Safety Data

• Hazardous Substances Data: 62337-90-0(Hazardous Substances Data)

Upstream product

• 14610-01-6 cyclohexylphosphinic acid ethyl ester 

Downstream Products

• 661486-76-6 t-Bu-c-HexPH-BH₃ 
• 1338696-68-6 chloro-(η5:η1[2-(tert-butylcyclohexylphosphanyl)ethyl]cyclopentadienyl)cobalt(II) 
• 1338696-72-2 (η5:η1[2-(tert-butylcyclohexylphosphanyl)ethyl]cyclopentadienyl)(η2-ethen)-rhodium(I) 

Relevant articles and documents

Copper-catalyzed C–P cross-coupling of secondary phosphines with (hetero)aromatic bromide

A novel and convenient approach to the synthesis of various tertiary phosphines via a copper-catalyzed cross-coupling of (hetero)aromatic bromide with secondary phosphines has been developed. The reaction employs cheap copper as the catalyst, 2,6-bis(N-methylaminomethyl)pyridine (L4) as a perfect ligand and KOtBu as a base; all reactions are carried out under argon atmosphere. A variety of sterically hindered and/or functionalized substrates were found to react under these reaction conditions to provide products in good to excellent yields. Moreover, ten new tertiary phosphines were first reported in this process.