625111-97-9

Basic information

• Product Name: 2,4-Imidazolidinedione, 5-[(1S)-1-methylpropyl]-, (5R)- (9CI)
• Synonyms: 2,4-Imidazolidinedione, 5-[(1S)-1-methylpropyl]-, (5R)- (9CI)
• CAS NO: 625111-97-9
• Molecular Formula: C7H12N2O2
• Molecular Weight: 156.18238
• Product Categories: ALCOHOL
• Mol File: 625111-97-9.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2,4-Imidazolidinedione, 5-[(1S)-1-methylpropyl]-, (5R)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Imidazolidinedione, 5-[(1S)-1-methylpropyl]-, (5R)- (9CI)(625111-97-9)
• EPA Substance Registry System: 2,4-Imidazolidinedione, 5-[(1S)-1-methylpropyl]-, (5R)- (9CI)(625111-97-9)

Safety Data

• Hazardous Substances Data: 625111-97-9(Hazardous Substances Data)

Usage

Compound group

imidazolidinediones

Structure

five-membered ring with four carbon atoms, one nitrogen atom, and two oxygen atoms

Derivative

2,4-imidazolidinedione

Configuration

(5R)-configuration

Usage

chemical and pharmaceutical research, potential applications in various fields

Upstream product

• 590-28-3 potassium cyanate 
• 18598-74-8 methyl L-isoleucinate hydrochloride 
• 3720-97-6 4,5-dihydroxy-2-imidazolidinone 
• 26117-19-1 (2S,3S)-3-methyl-2-ureidopentanoic acid 
• 461-72-3 2,4-imidazolidinedione 
• 78-93-3 butanone 
• 96-17-3 2-Methylbutyraldehyde 
• 1416815-98-9 C₈H₁₄N₂O₂ 
• 73-32-5 L-isoleucine 
• 42328-54-1 2-methyl butanal cyanohydrin 
• 506-87-6 ammonium carbonate 
• 111013-54-8 2-amino-3-methyl-valeronitrile; hydrochloride 

Downstream Products

• 2901-99-7 N-benzoyl-DL-alloisoleucine 

Relevant articles and documents

Preparation method of racemic ketoisoleucine calcium and intermediate thereof

The invention relates to a preparation method of racemic ketoisoleucine calcium and an intermediate thereof, the method comprises the following steps: reacting hydantoin and butanone in ammonia water to obtain sec-butyl hydantoin, adding strong base for reaction, and obtaining racemic ketoisoleucine salt with high yield and high purity without complex post-treatment steps. Calcium racemization ketoisoleucine can be prepared by using the calcium racemization ketoisoleucine salt prepared by the method, high-yield and high-purity calcium racemization ketoisoleucine can be obtained, the reaction solvent can be recycled and reused, the method is green and environment-friendly, and the problem of pollution to the environment is solved.

Dibutylphosphate (DBP) mediated synthesis of cyclic N,N′- disubstituted urea derivatives from amino esters: A comparative study

The N,N′-disubstituted urea derivatives such as amino acid hydantoins and dihydrouracil derivatives were prepared starting from natural and unnatural amino acid esters using dibutylphosphate (DBP). During the attempted synthesis of N-heterocycles with larger than six-membered rings containing the N,N′-disubstituted urea functionalities, three unexpected products namely squamolone, N-methyl pyrrolidine-2-one, and diketopiperazine were isolated.

Preparation of α-aminothioamides from aldehydes

The conversion of aldehydes into α-aminonitriles and thence into imidazolidin-4-thiones has been studied.Hydrolysis of the appropriate imidazolidin-4-thiones gave thioamides of nine naturally occuring α-amino acids.The possible pre-biotic significance of these compounds is discussed.