62559-36-8

Basic information

• Product Name: 1,3-Butanediol, 2-phenyl-
• CAS NO: 62559-36-8
• Molecular Formula: C10H14O2
• Molecular Weight: 166.22
• Mol File: 62559-36-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,3-Butanediol, 2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Butanediol, 2-phenyl-(62559-36-8)
• EPA Substance Registry System: 1,3-Butanediol, 2-phenyl-(62559-36-8)

Safety Data

• Hazardous Substances Data: 62559-36-8(Hazardous Substances Data)

Upstream product

• 244023-84-5 3-phenyl-1,5-dioxaspiro[3.2]hexane 
• 23355-97-7 1-phenylpropylene oxide 
• 872-38-8 2,3-epoxybutan-1-ol 
• 591-51-5 phenyllithium 
• 287411-54-5 [(4-(dimethyl-o-bromophenyl)silyloxy-butan-2-oxy)diphenylsilyl]trimethylsilane 

Relevant articles and documents

Acceleration of hetero-Michael reaction by symmetrical pentacyclic guanidines

Symmetrical pentacyclic guanidines 1a-c and 2 which contain the core skeleton of 13,14,15-isocrmbescidine 800, have been synthesized. In the presence of catalytic amounts of these guanidines 1, the reaction rate of the conjugate addition of pyrrolidine (9) to γ-crotonolactone (10) could be enhanced depending upon the size of the cavities and substituents on tetrahydropyran rings of 1 and 2.

Ring opening of 1,5-dioxaspiro[3.2]hexanes: Selective preparation of α-heterofunctionalized-β′-hydroxy ketones or 2,2-disubstituted oxetanes

(equation presented) 2-Methyleneoxetanes have been converted into 1,5-dioxaspiro[3.2]hexanes with dimethyldioxirane. Reaction of the dioxaspirohexanes with a range of heteroatom nucleophiles, hydride donors, or organoaluminum reagents was successful under

THE DIMESITYLBORON GROUP IN ORGANIC SYNTHESIS 8. PREPARATION OF 1,3-DIOLS FROM OXIRANES

Alkyldimesitylboranes, yield anions, Mes2BCHR, that on reaction with oxiranes followed by oxidation give 1,3-diols.These anions are thus the operational equivalent of RCHOH.The scope and limitations of the new process are delineated.