62754-67-0

Basic information

• Product Name: Phosphine oxide, diphenyl[3-(trifluoromethyl)phenyl]-
• CAS NO: 62754-67-0
• Molecular Formula: C19H14F3OP
• Molecular Weight: 346.289
• Mol File: 62754-67-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Phosphine oxide, diphenyl[3-(trifluoromethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine oxide, diphenyl[3-(trifluoromethyl)phenyl]-(62754-67-0)
• EPA Substance Registry System: Phosphine oxide, diphenyl[3-(trifluoromethyl)phenyl]-(62754-67-0)

Safety Data

• Hazardous Substances Data: 62754-67-0(Hazardous Substances Data)

Upstream product

• 644-97-3 Dichlorophenylphosphine 
• 172487-18-2 ethyl Phenylphosphinate 
• 401-78-5 3-bromo-1-trifluoromethylbenzene 
• 4559-70-0 Diphenylphosphine oxide 
• 1423-26-3 (meta-(trifluoromethyl)phenyl)boronic acid 
• 58710-61-5 phenyl 3-(trifluoromethyl)benzoate 

Relevant articles and documents

Visible-light-induced ligand to metal charge transfer excitation enabled phosphorylation of aryl halides

We herein described a visible light induced nickel(II)-catalyzed cross-coupling of secondary phosphine oxides with aryl halides. The Ni(I)species and chlorine atom radical Cl˙ were generatedviathe ligand to metal charge transfer (LMCT) process of the NiCl2(PPh3)2, which allows nickel(IV)-phosphorus speciesin situformation, giving various tertiary phosphine oxides under photocatalyst-free conditions.

Practical C–P bond formation via heterogeneous photoredox and nickel synergetic catalysis

An efficient C–P bond formation reaction was developed by virtue of the synergetic catalysis strategy by merging heterogeneous photocatalysis and nickel catalysis. This platform utilizing cadmium sulfide semiconductors as heterogeneous photocatalysts and

Palladium-catalyzed air-based oxidative coupling of arylboronic acids with H-phosphine oxides leading to aryl phosphine oxides

We present a novel and highly efficient methodology that allows for the construction of C-P bonds via the palladium-catalyzed air-based oxidative coupling of various commercially available arylboronic acids with easily oxidized H-phosphine oxides leading to valuable aryl phosphine oxides, particularly triarylphosphine oxides, with the use of air as the green oxidant, broad substrate applicability and good to excellent yields. The described catalytic system should be an efficient complement to the Chan-Lam type reaction and be useful in synthetic programs. This journal is the Partner Organisations 2014.