629-23-2

Basic information

• Product Name: 3-TETRADECANONE
• Synonyms: ETHYL N-UNDECYL KETONE;ETHYL UNDECYL KETONE;3-TETRADECANONE;tetradecanone;tetradecan-3-one;3-TETRADECANONE 95+%;3-TETRADECANONE 97%
• CAS NO: 629-23-2
• Molecular Formula: C₁₄H₂₈O
• Molecular Weight: 212.37
• EINECS: 211-081-9
• Product Categories: Aromatic Ketones (substituted)
• Mol File: 629-23-2.mol
• Article Data: 10

Chemical Properties

• Melting Point: 34 °C
• Boiling Point: 152 °C / 16mmHg
• Flash Point: 66 °C
• Appearance: /
• Density: 0.8256 (estimate)
• Vapor Pressure: 0.00528mmHg at 25°C
• Refractive Index: 1.4392 (estimate)
• CAS DataBase Reference: 3-TETRADECANONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-TETRADECANONE(629-23-2)
• EPA Substance Registry System: 3-TETRADECANONE(629-23-2)

Safety Data

• Hazardous Substances Data: 629-23-2(Hazardous Substances Data)

Usage

General Description

3-Tetradecanone is a ketone compound with the molecular formula C14H28O. It is a colorless liquid with a fruity, waxy odor, and it is commonly used as a flavoring agent and fragrance ingredient in the food and perfume industries. Its odor is reminiscent of peach and apricot, and it is often added to fruit-flavored products to enhance their aroma. 3-Tetradecanone is also used as a solvent in the production of various chemicals and as a raw material in the synthesis of pharmaceuticals and other organic compounds. Additionally, it has been studied for its potential insecticidal and antimicrobial properties, making it a versatile and valuable chemical in various industrial applications.

InChI:InChI=1/C14H28O/c1-3-5-6-7-8-9-10-11-12-13-14(15)4-2/h3-13H2,1-2H3

Upstream product

• 10467-10-4 ethylmagnesium iodide 
• 2437-25-4 undecyl cyanide 
• 557-91-5 1,1-Dibromoethane 
• 111-82-0 methyl n-dodecanoate 
• 110-53-2 1-Bromopentane 
• 17642-48-7 (+/-)-1-Tetradecen-3-ol 
• 74824-56-9 dec-1-en-3-ol 
• 4885-02-3 Dichloromethyl methyl ether 
• 87115-61-5 C₂₂H₃₉BO 
• 107-82-4 i-pentyl bromide 
• 1653-32-3 3-tetradecanol 
• 629-59-4 tetradecane 
• 63252-22-2 C₂₆H₃₇NO 
• 925-90-6 ethylmagnesium bromide 

Downstream Products

• 1653-32-3 3-tetradecanol 

Relevant articles and documents

Copper-catalyzed method for preparing aldehyde or ketone compound by oxidizing alcohol with oxygen as oxidizing agent and application

The invention discloses a copper-catalyzed method for preparing an aldehyde or ketone compound by oxidizing alcohol with oxygen as an oxidizing agent. Reaction is performed in an organic solvent for 4-48 hours at room temperature by using copper salt and nitroxide free radicals as catalysts and oxygen or air as an oxidizing agent to efficiently oxidize an alcohol compound into the corresponding aldehyde or ketone compound. The method is simple to operate, free of chlorides corrosive to equipment, available in raw materials and reagents, mild in reaction conditions, wide in substrate universality, good in functional group compatibility, convenient in separation and purification, environmentally friendly in the whole process and free of pollution, and is a method suitable for industrial production.

A general method for the direct transformation of common tertiary amides into ketones and amines by addition of Grignard reagents

The direct transformation of amides into ketones by addition of organometallic reagents has attracted the attention of organic chemists for a long time. However limited methods are reliable for common amides and have found synthetic applications. Here we report a method featuring in situ activation of tertiary amides with triflic anhydride (Tf2O) followed by addition of Grignard reagents. The method displays a good generality in scope for both amides and Grignard reagents, and it can be viewed as the acylation of Grignard reagents using amides as stable and selective acylating agents. Moreover, this deaminative alkylation reaction provides a mild method for the N-Deacylation of amides to give free amines.

Chemoselectivity in the ruthenium-catalyzed redox isomerization of allyl alcohols

Adjustment of oxidation level by internal hydrogen reorganization represents a highly efficient synthetic protocol. Cyclopentadienylbis(triphenylphosphine)ruthenium chloride in the presence of triethylammonium hexafluorophosphate catalyzes the redox isomerization of allyl alcohols to their saturated aldehydes or ketones. High chemoselectivity is observed since simple primary and secondary alcohols and isolated double bonds are not affected by this catalyst. The reaction is sensitive to the degree of substitution on the double bond and requires relatively unhindered olefins. Switching to indenylbis(triphenylphosphine)ruthenium chloride in the presence of triethylammonium hexafluorophosphate significantly expands the scope of the reaction to substrates bearing more substituted olefinic linkages and to cyclic substrates of rings containing eight or more members. The mechanism is probed by deuterium labeling, which shows that the metal catalyzes an intramolecular 1,3-hydrogen shift of the carbinol hydrogen to the terminal olefinic position.