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629-50-5

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629-50-5 Usage

Chemical Properties

colourless liquid

Uses

Different sources of media describe the Uses of 629-50-5 differently. You can refer to the following data:
1. Organic synthesis, distillation chaser.
2. n-Tridecane is used as a distillation chaser. It is a component of various fuels and solvents used in industry.

Synthesis Reference(s)

The Journal of Organic Chemistry, 46, p. 3909, 1981 DOI: 10.1021/jo00332a030Tetrahedron, 48, p. 8253, 1992 DOI: 10.1016/S0040-4020(01)80493-2

General Description

An oily straw yellow clear liquid with a hydrocarbon odor. Flash point 190-196°F. Specific gravity 0.76. Boiling point 456°F. Repeated or prolonged skin contact may irritate or redden skin, progressing to dermatitis. Exposure to high concentrations of vapor may result in headache and stupor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Saturated aliphatic hydrocarbons, such as n-Tridecane, may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, they burn exothermically to produce carbon dioxide and water.

Health Hazard

May be harmful by inhalation, ingestion or skin absorption. Vapor or mist is irritating to the eyes, mucous membrane and upper respiratory tract. Causes skin irritation.

Safety Profile

Moderately toxic by intravenousroute. When heated to decomposition it emits acrid smokeand irritating fumes.

Carcinogenicity

Mice treated with tridecane developed tumors on their backs, after exposure to ultraviolet radiation at wavelengths longer than 350 nm, generally considered noncarcinogenic.

Check Digit Verification of cas no

The CAS Registry Mumber 629-50-5 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 6,2 and 9 respectively; the second part has 2 digits, 5 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 629-50:
(5*6)+(4*2)+(3*9)+(2*5)+(1*0)=75
75 % 10 = 5
So 629-50-5 is a valid CAS Registry Number.
InChI:InChI=1/C13H28/c1-3-5-7-9-11-13-12-10-8-6-4-2/h3-13H2,1-2H3

629-50-5 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (A18220)  n-Tridecane, 98+%   

  • 629-50-5

  • 25g

  • 256.0CNY

  • Detail
  • Alfa Aesar

  • (A18220)  n-Tridecane, 98+%   

  • 629-50-5

  • 100g

  • 670.0CNY

  • Detail
  • Alfa Aesar

  • (A18220)  n-Tridecane, 98+%   

  • 629-50-5

  • 500g

  • 2680.0CNY

  • Detail
  • Sigma-Aldrich

  • (91490)  Tridecane  analytical standard

  • 629-50-5

  • 91490-5ML

  • 590.85CNY

  • Detail
  • Sigma-Aldrich

  • (91490)  Tridecane  analytical standard

  • 629-50-5

  • 91490-50ML

  • 3,806.01CNY

  • Detail
  • Supelco

  • (442713)  Tridecane  analytical standard

  • 629-50-5

  • 000000000000442713

  • 359.19CNY

  • Detail
  • Aldrich

  • (T57401)  Tridecane  ≥99%

  • 629-50-5

  • T57401-25G

  • 386.10CNY

  • Detail
  • Aldrich

  • (T57401)  Tridecane  ≥99%

  • 629-50-5

  • T57401-100G

  • 959.40CNY

  • Detail

629-50-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name tridecane

1.2 Other means of identification

Product number -
Other names Chloroform-13C,d

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:629-50-5 SDS

629-50-5Relevant articles and documents

CONTINUOUS PROCESS FOR THE PRODUCTION OF ALKANES

-

Page/Page column 12-13, (2021/11/13)

Continuous reductive dehydroxymethylation process for the preparation of alkanes from primary aliphatic alcohols, having 3 to 25 carbon atoms, in the presence of hydrogen and a catalyst in a reactor at a pressure of ≥ 2 bar, characterized in that the dehydroxymethylation takes place in the vapor phase.

Light-Driven Enzymatic Decarboxylation of Dicarboxylic Acids

Chen, Bi-Shuang,Liu, Lan,Zeng, Yong-Yi,Zhang, Wuyuan

, p. 553 - 559 (2021/06/25)

Photodecarboxylase from Chlorella variabillis (CvFAP) is one of the three known light-activated enzymes that catalyzes the decarboxylation of fatty acids into the corresponding C1-shortened alkanes. Although the substrate scope of CvFAP has been altered by protein engineering and decoy molecules, it is still limited to mono-fatty acids. Our studies demonstrate for the first time that long chain dicarboxylic acids can be converted by CvFAP. Notably, the conversion of dicarboxylic acids to alkanes still represents a chemically very challenging reaction. Herein, the light-driven enzymatic decarboxylation of dicarboxylic acids to the corresponding (C2-shortened) alkanes using CvFAP is described. A series of dicarboxylic acids is decarboxylated into alkanes in good yields by means of this approach, even for the preparative scales. Reaction pathway studies show that mono-fatty acids are formed as the intermediate products before the final release of C2-shortened alkanes. In addition, the thermostability, storage stability, and recyclability of CvFAP for decarboxylation of dicarboxylic acids are well evaluated. These results represent an advancement over the current state-of-the-art.

An unconventional DCOx favored Co/N-C catalyst for efficient conversion of fatty acids and esters to liquid alkanes

Li, Jiang,Liu, Jiaxing,Zhang, Junjie,Wan, Tong,Huang, Lei,Wang, Xintian,Pan, Runze,An, Zhidong,Vlachos, Dionisios G.

, (2019/12/26)

Cobalt (Co) catalysis has recently attracted significant attention in the field of biomass conversion. However, the fabrication of highly dispersive Co nanoparticles at high metal loading with selective facet exposure to achieve specific selectivity is still questionable. In this work, a nitrogen-doped carbon-supported Co catalyst is fabricated for efficient conversion of fatty acids and esters to liquid alkanes. Nitrogen-doping facilitates a highly uniform dispersion of Co nanoparticles even at a high Co loading of 10 wt% and after recycling for 5 runs. The Co/N-C catalyst affords an unconventional decarbonylation/decarboxylation (DCOx) dominant selectivity probably due to partial reduction of cobalt oxides to α-Co0 with only exposure of the (111) facet. Co-existence of Co and N-C leads to strong Lewis acidity and basicity, facilitating the interaction between catalyst and –COOH group, and some important acid-catalyzed step-reactions. The versatility of the Co/N-C catalyst is demonstrated through conversion of various fatty acids and esters.

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