63548-94-7Relevant articles and documents
Oxidation Reactions with HOF and Adducts of HOF and HF with Acetonitrile
Dunkelberg, Oliver,Haas, Alois,Klapdor, Martin Frank,Mootz, Dietrich,Poll, Wolfgang,Appelman, Evan Hugh
, p. 1871 - 1876 (2007/10/02)
In acetonitrile solution HOF oxides CF3SSCF3 via CF3S(O)nSCF3 (N = 1, 2) to yield 2O.Analogously, CF3Se(O)OH and CF3SeX (X = Cl, Br) are oxidized via CF3Se(VI) intermediates to provide finally 2O.With CH3CN at low temperatures HOF and HF for 1:1 adducts, whose structures have been elucidated by low-temperature X-ray structure analysis.Additional proof for the formation of CH3CN*HF in the liquid phase is provided. - Key Words: Oxidation by HOF / Hypofluorous acid / Addition compounds of HOF and HF with acetonitrile