639084-67-6

Basic information

• Product Name: 2-allyl-1-phenyl-pent-4-ene-1,2-diol
• Synonyms: 2-allyl-1-phenyl-pent-4-ene-1,2-diol
• CAS NO: 639084-67-6
• Molecular Weight: 218.296
• Mol File: 639084-67-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-allyl-1-phenyl-pent-4-ene-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-allyl-1-phenyl-pent-4-ene-1,2-diol(639084-67-6)
• EPA Substance Registry System: 2-allyl-1-phenyl-pent-4-ene-1,2-diol(639084-67-6)

Safety Data

• Hazardous Substances Data: 639084-67-6(Hazardous Substances Data)

Upstream product

• 4358-87-6 (RS)-methyl mandelate 
• 1730-25-2 allylmagnesium bromide 
• 106-95-6 allyl bromide 
• 774-40-3 hydroxy-phenyl-acetic acid ethyl ester 

Downstream Products

• 4176-76-5 1-(hydroxy-phenyl-methyl)-cyclopentanol 
• 639084-72-3 1-(hydroxy-phenyl-methyl)-cyclopent-3-enol 

Relevant articles and documents

Tandem olefin metathesis/hydrogenation at ambient temperature: Activation of ruthenium carbene complexes by addition of hydrides

Sodium hydride activates ruthenium carbene complexes to catalyze hydrogenation reactions subsequent to ring closing olefin metathesis. Under these conditions, hydrogenation of cyclopentenols proceeds smoothly at ambient temperature and under 1 atm of hydrogen in toluene. An alternative protocol was developed that involves the formation of hydrogen in situ by reaction of excess sodium hydride with protic functional groups and water.