64333-01-3

Basic information

• Product Name: MANGANESE(II) CHLORIDE HYDRATE
• Synonyms: MANGANESE CHLORIDE MONOHYDRATE;MANGANESE(II) CHLORIDE-1-HYDRATE;MANGANESE(II) CHLORIDE HYDRATE;MANGANESE (II) CHLORIDE, HYDROUS;MANGANESE(II) CHLORIDE MONOHYDRATE;MANGANESE(II) CHLORIDE-1-HYDRATE PURE;MANGANESE(II) CHLORIDE MONOHYDRATE 97+%;Manganese chloride (MnCl2), monohydrate
• CAS NO: 64333-01-3
• Molecular Formula: Cl2H2MnO
• Molecular Weight: 143.86
• EINECS: 231-869-6
• Product Categories: Catalysis and Inorganic Chemistry;Chemical Synthesis;Manganese
• Mol File: 64333-01-3.mol
• Article Data: 0

Chemical Properties

• Melting Point: 122 °C(lit.)
• Boiling Point: 85 oC (15 mmHg)
• Flash Point: 83 oC
• Appearance: /
• Density: 1.913 g/mL at 25 °C(lit.)
• Storage Temp.: Hygroscopic, Room Temperature, under inert atmosphere
• Solubility: Methanol (Slightly), Water (Slightly)
• CAS DataBase Reference: MANGANESE(II) CHLORIDE HYDRATE(CAS DataBase Reference)
• NIST Chemistry Reference: MANGANESE(II) CHLORIDE HYDRATE(64333-01-3)
• EPA Substance Registry System: MANGANESE(II) CHLORIDE HYDRATE(64333-01-3)

Safety Data

• Hazard Codes: Xn
• Statements: 22-36/37/38-52
• Safety Statements: 26-36/37-45-61-36-22
• WGK Germany: 1
• Hazardous Substances Data: 64333-01-3(Hazardous Substances Data)

Usage

Uses

Starting material for preparation of organomanganese chloride reagents; in combination with RLi or RMgX catalyzes reduction of vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- andstereo-selectively.

InChI:InChI=1/2ClH.Mn.H2O/h2*1H;;1H2/q;;+2;/p-2