64436-62-0Relevant articles and documents
Green synthesis method of polyaryl substituted methanol
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Paragraph 0127-0131; 0307-0311, (2021/04/17)
The invention relates to a green synthesis method of polyaryl substituted methanol, in particular to a method for efficiently synthesizing polyaryl substituted methanol in a polar aprotic solvent under the condition of an oxidizing agent by taking polyaryl substituted methane as a raw material and alkali as an additive. The method provided by the invention is green and environment-friendly, avoids using expensive metal catalysts, and has the advantages of low cost, few reaction steps, short time, high yield and the like.
Organic compound containing fluorene and pyridino-indole and application thereof
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Paragraph 0035-0037, (2019/04/17)
The invention relates to an organic compound containing fluorene and pyridino-indole and an application thereof in organic light emission diodes devices. The compound utilized a benzo five-membered ring as a core and is connected with a pyridyl group or a pyridino-indole group. The compound of the invention has high glass transition temperature and high bond dissociation energy, so that the service life of the OLED devices can be improved; the compound also has a deep HOMO energy level and high electron mobility, and can be used as hole blocking layer/electron transfer layer materials of the OLED devices or a material of a partial electron type main body, holes or energy can be effectively blocked from being transmitted from a light emitting layer to one side of an electron layer, therebyimproving the recombination efficiency of holes and electrons in the light emitting layer, and the luminous efficiency of the OLED devices is improved.
Indolopyridines with a bridging heteroatom. 9. Synthesis, structure, and thermolysis of 5-hydroxy-5-(2-pyridyl)-fluorene and -4-azafluorene
Soldatenkov,Kolyadina,Kuleshova,Khrustalev
, p. 817 - 821 (2007/10/03)
Treatment of fluorenone or 4-azafluoren-9-one with 2-pyridyllithium gives 5-hydroxy-5-(2-pyridyl)fluorene and its aza analog. The structure of the former has been studied by x-ray crystallography. It was found that, in contrast to the non-condensed diaryl-2-pyridylcarbinols, these alcohols do not undergo acid catalyzed dehydration and heterocyclization. Under pyrolytic conditions, 5-pyridylfluorenol undergoes fission to form fluorenone. 1997 Plenum Publishing Corporation.