64437-82-7

Basic information

• Product Name: Acetic acid, [dimethyl(4-methylphenyl)silyl]-, ethyl ester
• CAS NO: 64437-82-7
• Molecular Formula: C13H20O2Si
• Molecular Weight: 236.386
• Mol File: 64437-82-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid, [dimethyl(4-methylphenyl)silyl]-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, [dimethyl(4-methylphenyl)silyl]-, ethyl ester(64437-82-7)
• EPA Substance Registry System: Acetic acid, [dimethyl(4-methylphenyl)silyl]-, ethyl ester(64437-82-7)

Safety Data

• Hazardous Substances Data: 64437-82-7(Hazardous Substances Data)

Upstream product

• 2417-95-0 p-tolyllithium 
• 623-73-4 diazoacetic acid ethyl ester 
• 1432-39-9 dimethyl-p-tolylsilane 

Relevant articles and documents

Au Nanoparticle-Catalyzed Insertion of Carbenes from α-Diazocarbonyl Compounds into Hydrosilanes

Supported Au nanoparticles on TiO2 catalyze the insertion of carbenes from α-diazocabonyl compounds into hydrosilanes. It is proposed that the transformation involves two modes of catalytic activation: formation of nucleophilic Au carbenes on the surface of nanoparticle via expulsion of N2 and activation of the Si-H bond of hydrosilane on Au nanoparticle, followed by coupling of the chemisorbed species. No external ligands or additives are required, while the process is purely heterogeneous, thus allowing the recycling and reuse of the catalyst.