644981-53-3

Basic information

• Product Name: tri-tert-butyl (1S,3S,4S,5R,6R,7R)-6-benzyloxy-7-(tert-butoxycarbonyl)oxy-4-hydroxy-1-[2-(methoxymethoxy)ethyl]-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate
• Synonyms: tri-tert-butyl (1S,3S,4S,5R,6R,7R)-6-benzyloxy-7-(tert-butoxycarbonyl)oxy-4-hydroxy-1-[2-(methoxymethoxy)ethyl]-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate
• CAS NO: 644981-53-3
• Molecular Weight: 740.843
• Mol File: 644981-53-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tri-tert-butyl (1S,3S,4S,5R,6R,7R)-6-benzyloxy-7-(tert-butoxycarbonyl)oxy-4-hydroxy-1-[2-(methoxymethoxy)ethyl]-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: tri-tert-butyl (1S,3S,4S,5R,6R,7R)-6-benzyloxy-7-(tert-butoxycarbonyl)oxy-4-hydroxy-1-[2-(methoxymethoxy)ethyl]-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate(644981-53-3)
• EPA Substance Registry System: tri-tert-butyl (1S,3S,4S,5R,6R,7R)-6-benzyloxy-7-(tert-butoxycarbonyl)oxy-4-hydroxy-1-[2-(methoxymethoxy)ethyl]-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate(644981-53-3)

Safety Data

• Hazardous Substances Data: 644981-53-3(Hazardous Substances Data)

Upstream product

• 71432-55-8 2-tert-butyl-1,3-diisopropylisourea 
• 24424-99-5 di-tert-butyl dicarbonate 
• 644981-51-1 di-tert-butyl (1S,3R,4S,5R,6R,7R)-6-benzyloxy-7-(tert-butoxycarbonyl)oxy-3-[(tert-butyldiphenylsilyl)oxymethyl]-1-[2-(methoxymethoxy)ethyl]-4-(trimethylsilyl)oxy-2,8-dioxabicyclo[3.2.1]octane-4,5-dicarboxylate 
• 644981-48-6 di-tert-butyl (1S,3R,4S,5R,6R,7R)-7-acetyl-6-benzyloxy-3-[(tert-butyldiphenylsilyl)oxymethyl]-7-hydroxy-1-[2-(methoxymethoxy)ethyl]-4-(trimethylsilyl)oxy-2,8-dioxabicyclo[3.2.1]octane-4,5-dicarboxylate 
• 925453-59-4 di-tert-butyl (1S,3R,4S,5R,6R,7S)-6-benzyloxy-3-[(tert-butyldiphenylsilyl)oxymethyl]-7-hydroxy-7-(1-hydroxyethyl)-1-[2-(methoxymethoxy)ethyl]-4-(trimethylsilyl)oxy-2,8-dioxabicyclo[3.2.1]octane-4,5-dicarboxylate 
• 644981-50-0 di-tert-butyl (1S,3R,4S,5R,6R,7R)-6-benzyloxy-3-[(tert-butyldiphenylsilyl)oxymethyl]-7-hydroxy-1-[2-(methoxymethoxy)ethyl]-4-(trimethylsilyl)oxy-2,8-dioxabicyclo[3.2.1]octane-4,5-dicarboxylate 
• 644981-49-7 di-tert-butyl (1S,3R,4S,5R,6S)-6-benzyloxy-3-[(tert-butyldiphenylsilyl)oxymethyl]-1-[2-(methoxymethoxy)ethyl]-7-oxo-4-(trimethylsilyl)oxy-2,8-dioxabicyclo[3.2.1]octane-4,5-dicarboxylate 
• 644981-47-5 di-tert-butyl (1S,3R,4S,5R,6R,7R)-7-acetyl-3-[(tert-butyldiphenylsilyl)oxymethyl]-6,7-dihydroxy-1-[2-(methoxymethoxy)ethyl]-4-(trimethylsilyl)oxy-2,8-dioxabicyclo[3.2.1]octane-4,5-dicarboxylate 
• 644981-46-4 di-tert-butyl (1S,3R,4S,5R)-7-acetyl-3-[(tert-butyldiphenylsilyl)oxymethyl]-1-[2(methoxymethoxy)ethyl]-4-(trimethylsilyl)oxy-2,8-dioxabicyclo[3.2.1]oct-6-ene-4,5-dicarboxylate 
• 644981-52-2 di-tert-butyl (1S,3R,4S,5R,6R,7R)-6-benzyloxy-7-(tert-butoxycarbonyl)oxy-4-hydroxy-3-(hydroxymethyl)-1-[2-(methoxymethoxy)ethyl]-2,8-dioxabicyclo[3.2.1]octane-4,5-dicarboxylate 
• 100-39-0 benzyl bromide 
• 644981-45-3 di-tert-butyl [2R,2(1R)]-2-[2-(tert-butyldiphenylsilyl)oxy-1-[3-(methoxymethoxy)propionyl]oxyethyl]-3-diazo-2-(trimethylsilyl)oxybutanedioate 
• 644981-38-4 tert-butyl (2S,3R)-4-(tert-butyldiphenylsilyl)oxy-2-hydroxy-3-(4-methoxybenzyl)oxybutanoate 
• 644981-42-0 tert-butyl (2S,3R)-4-(tert-butyldiphenylsilyl)oxy-2-hydroxy-3-[3-(methoxymethoxy)propionyl]oxybutanoate 

Downstream Products

• 925453-22-1 tri-tert-butyl (1S,3S,4S,5R,6R,7R)-6-benzyloxy-7-(tert-butoxycarbonyl)oxy-1-(formylmethyl)-4-hydroxy-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate 
• 925453-61-8 tri-tert-butyl (1S,3S,4S,5R,6R,7R)-6-benzyloxy-7-(tert-butoxycarbonyl)oxy-4-hydroxy-1-(2-hydroxyethyl)-2,8-dioxabicyclo[3.2.1]octane-3,4,5-tricarboxylate 

Relevant articles and documents

Total syntheses of zaragozic acids A and C by a carbonyl ylide cycloaddition strategy

A carbonyl ylide cycloaddition approach to the squalene synthase inhibitors zaragozic acids A and C is described. The carbonyl ylide precursor 8 was synthesized starting from di-tert-butyl D-tartrate (47) via an eleven-step sequence involving the regiosel