646039-18-1

Basic information

• Product Name: Quinoline, 3,4-dihydro-6-methoxy-2-methyl- (9CI)
• Synonyms: Quinoline, 3,4-dihydro-6-methoxy-2-methyl- (9CI)
• CAS NO: 646039-18-1
• Molecular Formula: C₁₁H₁₃NO
• Molecular Weight: 175.22702
• Product Categories: METHOXY
• Mol File: 646039-18-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Quinoline, 3,4-dihydro-6-methoxy-2-methyl- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Quinoline, 3,4-dihydro-6-methoxy-2-methyl- (9CI)(646039-18-1)
• EPA Substance Registry System: Quinoline, 3,4-dihydro-6-methoxy-2-methyl- (9CI)(646039-18-1)

Safety Data

• Hazardous Substances Data: 646039-18-1(Hazardous Substances Data)

Upstream product

• 591-31-1 3-methoxy-benzaldehyde 
• 123-11-5 4-methoxy-benzaldehyde 
• 20766-31-8 4-(3-methoxyphenyl)but-3-en-2-one 
• 29114-51-0 4-(3-methoxyphenyl)butan-2-one 
• 104-20-1 4-(4-methoxyphenyl)-2-butanone 
• 943-88-4 4-(p-methoxyphenyl)-3-butene-2-one 
• 191484-60-3 (E)-4-(4-methoxyphenyl)butan-2-one oxime 
• 191484-58-9 (E)-4-(3-methoxyphenyl)butan-2-one oxime 

Downstream Products

• 1078-28-0 6-methoxyquinaldine 
• 42835-96-1 6-methoxy-2-methyl-1,2,3,4-tetrahydroquinoline 

Relevant articles and documents

Synthesis of Quinolines and 2H-Dihydropyrroles by Nucleophilic Substitution at the Nitrogen Atom of Oxime Derivatives

Isomerization of oxime derivatives was researched in detail to find out the methods for the syn-anti isomerization of O-substituted oximes. Based on these findings were developed simple methods for the preparation of aza-heterocycles from both stereoisomers of oximes. Quinolines were synthesized from β-aryl ketone oximes by treatment with trifluoroacetic anhydride and 4-chloranil. γ,δ-Unsaturated O-methoxyacetyloximes were transformed to 2H-dihydropyrroles by reaction with methoxy-acetic acid.