64709-75-7

Basic information

• Product Name: Methanaminium, N-methyl-N-oxo-
• CAS NO: 64709-75-7
• Molecular Formula: C2H6NO
• Molecular Weight: 60.0757
• Mol File: 64709-75-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methanaminium, N-methyl-N-oxo-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanaminium, N-methyl-N-oxo-(64709-75-7)
• EPA Substance Registry System: Methanaminium, N-methyl-N-oxo-(64709-75-7)

Safety Data

• Hazardous Substances Data: 64709-75-7(Hazardous Substances Data)

Upstream product

• 6130-87-6 Tetramethyltetrazon 

Downstream Products

• 87-52-5 C₁₁H₁₄N₂⁽¹⁺⁾ 

Relevant articles and documents

Gas-Phase Reactions of (CH3)2N Radicals with NO and NO2

The absolute rate constants for the reactions of (CH3)2N radicals with NO and NO2 were determined in the gas phase and at room temperature by using the very low pressure reactor (VLPR) technique.The rates were k(CH3)2N + NO = (8.53 +/- 1.42) x 1E-14 Cm3 molecule-1s-1 and k(CH3)2N + NO2 = (9.08 +/- 1.36) x 1E-13 cm3 molecule-1s-1.The reaction with NO2 proceeds via two competitive pathways: the recombination patway (CH3)2N + NO2 -> (CH3)2NNO2, with a rate constant k2a = (3.18 +/- 0.48) x 1E-13 cm3molecule-1s-1, and the oxidation patway (CH3)2N + NO2 -> (CH3)2NONO* -> (CH3)2NO + NO, with a rate constant k2b = (6.36 +/- 0.74) x 1E-13 cm3molecule-1s-1.The oxidation pathway is ca. 2.2 times faster than the recombination one, and the ratio k2a/k2b = 0.45 +/- 0.15.Conventional transition state theory analysis indicates that the involved transition states are loose, with the NN or bond lengths equal to ca. 2.5 Angstroem.