647824-13-3

Basic information

• Product Name: N-(2-chlorobenzylidene)-N',N'-dimethyl-1,3-propanediamine
• CAS NO: 647824-13-3
• Molecular Weight: 224.733
• Mol File: 647824-13-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-(2-chlorobenzylidene)-N',N'-dimethyl-1,3-propanediamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-chlorobenzylidene)-N',N'-dimethyl-1,3-propanediamine(647824-13-3)
• EPA Substance Registry System: N-(2-chlorobenzylidene)-N',N'-dimethyl-1,3-propanediamine(647824-13-3)

Safety Data

• Hazardous Substances Data: 647824-13-3(Hazardous Substances Data)

Upstream product

• 89-98-5 2-chloro-benzaldehyde 
• 109-55-7 1-amino-3-(dimethylamino)propane 

Downstream Products

• 339524-73-1 (C₆H₄CHN(CH₂)3N(CH₃)2)Pd(P₂(C₆H₅)4C₂H₂)⁽¹⁺⁾*ClO₄^(1-)=(C₆H₄CHN(CH₂)3N(CH₃)2)Pd(P₂(C₆H₅)4C₂H₂)ClO₄ 
• 339524-56-0 (C₆H₄CHN(CH₂)3N(CH₃)2)Pd(P(C₆H₅)3)⁽¹⁺⁾*CF₃SO₃^(1-)=(C₆H₄CHN(CH₂)3N(CH₃)2)Pd(P(C₆H₅)3)(CF₃SO₃) 
• 339524-71-9 ((C₆H₄CHN(CH₂)3N(CH₃)2)PdI)2((C₆H₅)2P(CH₂)5P(C₆H₅)2) 
• 339524-68-4 ((C₆H₄CHN(CH₂)3N(CH₃)2)PdI)2((C₆H₅)2P(CH₂)4P(C₆H₅)2) 
• 339524-70-8 ((C₆H₄CHN(CH₂)3N(CH₃)2)PdBr)2((C₆H₅)2P(CH₂)5P(C₆H₅)2) 
• 339524-69-5 ((C₆H₄CHN(CH₂)3N(CH₃)2)PdCl)2((C₆H₅)2P(CH₂)5P(C₆H₅)2) 
• 339524-67-3 ((C₆H₄CHN(CH₂)3N(CH₃)2)PdBr)2((C₆H₅)2P(CH₂)4P(C₆H₅)2) 
• 339524-66-2 ((C₆H₄CHN(CH₂)3N(CH₃)2)PdCl)2((C₆H₅)2P(CH₂)4P(C₆H₅)2) 
• 339524-59-3 (C₆H₄CHN(CH₂)3N(CH₃)2)Pd(P(C₆H₅)3)I 
• 339524-57-1 (C₆H₄CHN(CH₂)3N(CH₃)2)Pd(P(C₆H₅)3)Cl 
• 339524-58-2 (C₆H₄CHN(CH₂)3N(CH₃)2)Pd(P(C₆H₅)3)Br 
• 339524-60-6 (C₆H₄CHN(CH₂)3N(CH₃)2)Pd(PCH₃(C₆H₅)2)Cl 
• 339524-61-7 (C₆H₄CHN(CH₂)3N(CH₃)2)Pd(P(CH₃)2C₆H₅)Cl 
• 867313-11-9 [PtCl₂(N-(2-chlorobenzylidene)-N',N'-dimethyl-1,3-propanediamine)] 

Relevant articles and documents

Synthesis and reactivity of cyclometallated platinum (II) compounds containing [C,N,N′] terdentate ligands: Crystal structures of [PtCl{(CH3)2N(CH2)3NCH(4-ClC 6H3)}], [PtCl{(CH3)2N(CH 2)3NCH(2-ClC6H3)}]

The reaction of compound cis-[PtCl2(dmso)2] with ligands RCHN(CH2)3NMe2 (1a-1h) in which R is a phenyl group containing substituents such as Cl, F, Me, NO2 and MeO produced compounds [PtCl2{(CH3)2N(CH 2)3NCHR}] (2), as mixtures of Z and E isomers. When treated with an equimolar amount of sodium acetate in refluxing methanol compounds 2 gave cyclometallated platinum compounds 3 containing a terdentate [C,N,N′] ligand. The obtained compounds were fully characterized including structure determinations for compounds 3a, 3b and 3e. The effects of the substituents in the regioselectivity of the cyclometallation reaction and the reactivity of 3a and 3b with mono and bidentate phosphines were also studied.