648424-43-5

Basic information

• Product Name: 1-HEXYL-3-METHYLIMIDAZOLIUM PERCHLORATE
• Synonyms: 1-HEXYL-3-METHYLIMIDAZOLIUM PERCHLORATE;3-Hexyl-1-methyl-1H-imidazolium perchlorate;HMIMClO4
• CAS NO: 648424-43-5
• Molecular Formula: C10H19ClN2O4
• Molecular Weight: 266.72186
• Mol File: 648424-43-5.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-HEXYL-3-METHYLIMIDAZOLIUM PERCHLORATE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-HEXYL-3-METHYLIMIDAZOLIUM PERCHLORATE(648424-43-5)
• EPA Substance Registry System: 1-HEXYL-3-METHYLIMIDAZOLIUM PERCHLORATE(648424-43-5)

Safety Data

• Hazardous Substances Data: 648424-43-5(Hazardous Substances Data)

Usage

General Description

1-Hexyl-3-Methylimidazolium Perchlorate is a type of ionic liquid, which are salts that typically remain in a liquid state under standard conditions. 1-HEXYL-3-METHYLIMIDAZOLIUM PERCHLORATE is known for its useful chemical properties such as low volatility, non-flammability, and excellent thermal stability. These features make it particularly valuable in various industrial applications, such as in electrochemical systems and as a solvent in organic synthesis. It also has potential in other areas such as materials processing, lubrication, and nuclear fuel recycling. However, like many ionic liquids, its environmental impact and toxicity are subjects of ongoing research.

Upstream product

• 616-47-7 1-methyl-1H-imidazole 
• 111-25-1 1-bromo-hexane 
• 544-10-5 1-Chlorohexane 

Relevant articles and documents

Thermodynamic and molecular origin of interfacial rate enhancements and endo -selectivities of a Diels-Alder reaction

Organic reactions in general display large rate accelerations when performed under interfacial conditions, such as on water or at ionic liquid interfaces. However, a clear picture of the physicochemical factors responsible for this large rate enhancements is not available. To gain an understanding of the thermodynamic and molecular origin of these large rate enhancements, we performed a Diels-Alder reaction between cyclopentadiene and methyl acrylate at ionic liquid/n-hexane interfaces. This study describes, for the first time, a methodology for the calculation of the activation parameters of an interfacial reaction. It has been seen that the energy of activation for an interfacial reaction is much smaller than that of the corresponding homogeneous reaction, resulting into the large rate acceleration for the interfacial reaction. Furthermore, the study describes the effects of the alkyl chain length of ionic liquid cations, the extent of heterogeneity, and the polarity of ionic liquids on the rate constants and stereoselectivity of the reaction.