648904-00-1

Basic information

• Product Name: methyl (ethyl 2,3-di-O-benzyl-4-O-chloroacetyl-1-thio-β-D-glucopyranosid)uronate
• Synonyms: methyl (ethyl 2,3-di-O-benzyl-4-O-chloroacetyl-1-thio-β-D-glucopyranosid)uronate
• CAS NO: 648904-00-1
• Molecular Weight: 509.02
• Mol File: 648904-00-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (ethyl 2,3-di-O-benzyl-4-O-chloroacetyl-1-thio-β-D-glucopyranosid)uronate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (ethyl 2,3-di-O-benzyl-4-O-chloroacetyl-1-thio-β-D-glucopyranosid)uronate(648904-00-1)
• EPA Substance Registry System: methyl (ethyl 2,3-di-O-benzyl-4-O-chloroacetyl-1-thio-β-D-glucopyranosid)uronate(648904-00-1)

Safety Data

• Hazardous Substances Data: 648904-00-1(Hazardous Substances Data)

Upstream product

• 346435-04-9 Ethyl 2,3-di-O-benzyl-6-O-triphenylmethyl-1-thio-β-D-glucopyranoside 
• 67-56-1 methanol 

Relevant articles and documents

Synthesis of tetra- and pentasaccharides corresponding to the capsular polysaccharide of Streptococcus pneumoniae type 9A&L, 9N and 9A

Two tetrasaccharides, α-D-GlcAp-(1→3)-α-D-Galp-(1→3)- β-D-ManpNAc-(1→4)-β-D-Glcp and α-D-GlcAp-(1→3)- α-D-Glcp-(1→3)-β-D-ManpNAc-(1→4)-β-D-Glcp (protected form), and a pentasaccharide, α-D-Glcp-(1→4)-α-D-GlcAp- (1→3)-α-D-Galp-(1→3)-β-D-ManpNAc-(1→4)-β-D-Glcp have been synthesised from 2-aminoethyl glycoside trisaccharide acceptors in a linear approach via consecutive α-glycosylations. Ethyl thioglycosides were used as glycosyl donors and DMTST in Et2O or NIS/TfOH in CH 2Cl2 were employed as promoters.