651738-37-3

Basic information

• Product Name: Silane, [(2E)-1-methoxy-3-[(4-methylphenyl)sulfonyl]-2-propenyl]trimethyl-
• CAS NO: 651738-37-3
• Molecular Formula: C14H22O3SSi
• Mol File: 651738-37-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, [(2E)-1-methoxy-3-[(4-methylphenyl)sulfonyl]-2-propenyl]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(2E)-1-methoxy-3-[(4-methylphenyl)sulfonyl]-2-propenyl]trimethyl-(651738-37-3)
• EPA Substance Registry System: Silane, [(2E)-1-methoxy-3-[(4-methylphenyl)sulfonyl]-2-propenyl]trimethyl-(651738-37-3)

Safety Data

• Hazardous Substances Data: 651738-37-3(Hazardous Substances Data)

Upstream product

• 41208-03-1 2-(4-tolylthio)acetaldehyde 
• 14704-14-4 (methoxymethyl)trimethylsilane 

Relevant articles and documents

"Syn-Effect" in the Desilylation Reaction of γ-Silylated Allylic and Vinylic Sulfones

The desilylation reaction of γ-silylated allylic sulfones was found to proceed through γ-silylated (E)-vinylic sulfones to afford the corresponding allylic sulfones by treatment with DBU and H2O. The Z/ E ratio of the resulting allylic sulfones varied according to the γ-substituents of the γ-silylated sulfones. This stereo-chemical outcome was rationalized by "syn-effect".