654670-50-5

Basic information

• Product Name: [NiCl₃(NC(CH₃)CHC(CH₃)NCH₂CH₂SSCH₂CH₂NC(CH₃)CHC(CH₃)NH)]
• Synonyms: [NiCl₃(NC(CH₃)CHC(CH₃)NCH₂CH₂SSCH₂CH₂NC(CH₃)CHC(CH₃)NH)]
• CAS NO: 654670-50-5
• Molecular Weight: 476.544
• Mol File: 654670-50-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [NiCl₃(NC(CH₃)CHC(CH₃)NCH₂CH₂SSCH₂CH₂NC(CH₃)CHC(CH₃)NH)](CAS DataBase Reference)
• NIST Chemistry Reference: [NiCl₃(NC(CH₃)CHC(CH₃)NCH₂CH₂SSCH₂CH₂NC(CH₃)CHC(CH₃)NH)](654670-50-5)
• EPA Substance Registry System: [NiCl₃(NC(CH₃)CHC(CH₃)NCH₂CH₂SSCH₂CH₂NC(CH₃)CHC(CH₃)NH)](654670-50-5)

Safety Data

• Hazardous Substances Data: 654670-50-5(Hazardous Substances Data)

Upstream product

• 18182-48-4 1-(2-mercaptoethyl)-3,5-dimethylpyrazole 

Relevant articles and documents

Synthesis, X-ray crystal structure, and NMR characterisation of thiolate-bridged dinuclear Ni(II), Pd(II) and Pt(II) complexes of didentate ligands with NS-donor set

Thiolate-bridged dinuclear nickel(II), palladium(II) and platinum(II) complexes with N-(2-mercaptoethyl)-3,5-dimethylpyrazole (Hmed), [MCl(med)] 2 (M=Ni (1), Pd (2), Pt (3)), have been synthesised and characterised by elemental analyses, conductivity, IR, electronic spectra and NMR spectroscopies. The crystal structure of 2 was determined by a single-crystal X-ray diffraction method. The structure consists of thiolate-bridged dinuclear units. Each Pd(II) atom is coordinated by a pyrazolic nitrogen, one chlorine and two bridging sulfur atoms. When the synthesis of complex 1 was carried out in acetonitrile and in the presence of oxygen, [NiCl3(Hdeds)] (4) was formed (deds=1,1′- (dithiodiethylene)bis(3,5-dimethylpyrazole)). The crystal structure of this complex was also determined by single-crystal X-ray diffraction method. The structure consists of nickel(II) ions coordinated by three chloride ions and one pyrazolic nitrogen atom. Ligand deds is the result of the oxidation of N-(2-mercaptoethyl)-3,5-dimethylpyrazole (Hmed).