658044-18-9

Basic information

• Product Name: [(p-cymene)RuCl₂]₂
• CAS NO: 658044-18-9
• Molecular Weight: 611.386
• Mol File: 658044-18-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [(p-cymene)RuCl₂]₂(CAS DataBase Reference)
• NIST Chemistry Reference: [(p-cymene)RuCl₂]₂(658044-18-9)
• EPA Substance Registry System: [(p-cymene)RuCl₂]₂(658044-18-9)

Safety Data

• Hazardous Substances Data: 658044-18-9(Hazardous Substances Data)

Upstream product

• 123143-62-4 Ru(η6-p.cymene)(η4-cycloocta-1,5-diene) 
• 7647-01-0 hydrogenchloride 
• 281676-60-6 [(p-Me-C6H4-CH(CH3)2)2Ru2Cl2(μ-Cl)(μ-H)] 

Downstream Products

• 1253586-74-1 [ruthenium(II)chloride(η6-p-cymene)(N-[2-(phenylseleno)ethyl]morpholine)](hexafluorophosphate) 
• 1253586-68-3 [ruthenium(II)chloride(η6-p-cymene)(N-[2-(phenylsulfo)ethyl]morpholine)](hexafluorophosphate) 
• 1070163-24-4 (η6-1-isopropyl-4-methylbenzene)(N-(p-tosyl)-ortho-diaminobenzene)ruthenium(II) 
• 1070163-25-5 (η6-1-isopropyl-4-methylbenzene)(N-(p-tosyl)-1,2-diamino-1,1,2,2-tetramethylethane)ruthenium(II) 
• 478921-33-4 [Ru(II)Cl(η6-p-methylisopropylbenzene)(diazepam)] 
• 210763-84-1 ((CH₃)2CHC₆H₄CH₃)RuCl(SP(C₆H₅)2)2N 
• 210763-85-2 ((CH₃)2CHC₆H₄CH₃)RuCl(SeP(C₆H₅)2)2N 
• 169897-44-3 (CH₃C₆H₄CH(CH₃)2)RuCl₂(P(OC₆H₃F₂)3) 
• 1415227-07-4 C₂₅H₂₆ClN₃Ru 
• 265659-54-9 (η6-p-cymene)RuCl((4,4'-dimethyl)-(phenylazo)phenyl) 
• 265659-53-8 (η6-p-cymene)RuCl(phenylazophenyl) 

Relevant articles and documents

Reactivity of dinuclear arene ruthenium complexes: Reactions of the hydrido complex [(p-Me-C6H4-Pri)2Ru 2Cl2(μ-Cl)(μ-H)] with NaX and HX (X=F, Cl, Br, I)

The dinuclear hydrido complex [(p-Me-C6H4-Pri)2Ru 2Cl2(μ-Cl)(μ-H)] (1) reacts with the sodium halides NaX in methanol to give the halogen analogues [(p-Me-C6H4-Pri)2Ru 2X2(μ-X)(μ-H)] (2: X=F, 3: X=Br, 4: X=I). With HX, complex 1 reacts to give the tetrahalo complexes [(p-Me-C6H4-Pri)2Ru 2X2(μ-X)2] (5: X=Cl, 6: X=Br, 7: X=I); in the case of X=I, a large excess of HI leads to the formation of the cationic complex [(p-Me-C6H4-Pri)2Ru 2(μ-I)3]+ (8). The X-ray structure analysis of 1 shows a dinuclear Ru2 backbone with two terminal chloro ligands being trans with respect to each other as the two p-cymene ligands, the two bridging ligands lie in a plane perpendicular to the plane defined by the terminal chloro ligands and the ruthenium atoms.