65851-20-9Relevant articles and documents
ALDEHYDE-SELECTIVE WACKER-TYPE OXIDATION OF UNBIASED ALKENES
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Paragraph 0178-0183, (2014/10/29)
This disclosure is directed to methods of preparing organic aldehydes, each method comprising contacting a terminal olefin with an oxidizing mixture comprising: (a) a dichloro-palladium complex; (b) a copper complex; (c) a source of nitrite; under aerobic reaction conditions sufficient to convert at least a portion of the terminal olefin to an aldehyde.
Novel radical reaction of phenylsulfonyl oxime ethers. A free radical acylation approach
Kim, Sunggak,Lee, Ill Young,Yoon, Joo-Yong,Oh, Dong Hyun
, p. 5138 - 5139 (2007/10/03)
Although acylation represents one of the most useful and thoroughly studied reactions in organic chemistry, a successful free radical mediated acylation is not presently available. free radical carbonylation has recently been reported. This reaction allow