66039-65-4

Basic information

• Product Name: {bis(triphenylphosphine)nitrogen}2{(iron)3(carbonyl)11}
• Synonyms: {bis(triphenylphosphine)nitrogen}2{(iron)3(carbonyl)11}
• CAS NO: 66039-65-4
• Molecular Weight: 1552.83
• Mol File: 66039-65-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {bis(triphenylphosphine)nitrogen}2{(iron)3(carbonyl)11}(CAS DataBase Reference)
• NIST Chemistry Reference: {bis(triphenylphosphine)nitrogen}2{(iron)3(carbonyl)11}(66039-65-4)
• EPA Substance Registry System: {bis(triphenylphosphine)nitrogen}2{(iron)3(carbonyl)11}(66039-65-4)

Safety Data

• Hazardous Substances Data: 66039-65-4(Hazardous Substances Data)

Upstream product

• 17685-52-8 triiron dodecarbonyl 
• 119207-87-3 [bis(triphenylphospine)nitrogen⁽¹⁺⁾][Re(CO)5] 
• 52542-59-3 bis(triphenylphosphineiminium) pentacarbonylmanganate^(1-) 
• 21050-13-5 bis(triphenylphosphine)iminium chloride 

Downstream Products

• 72251-85-5 [((C₆H₅)3P)2N]⁽¹⁺⁾*[Fe₃Co(CO)13]^(1-) = [((C₆H₅)3P)2N][Fe₃Co(CO)13] 
• 17685-52-8 triiron dodecarbonyl 
• 52542-59-3 bis(triphenylphosphineiminium) pentacarbonylmanganate^(1-) 
• 13463-40-6 iron pentacarbonyl 
• 10170-69-1 dimanganese decacarbonyl 
• 84143-94-2 FeMn^(1-)*9CO=FeMn(CO)9^(1-) 
• 38117-54-3 cyclopentadienyl iron(II) dicarbonyl dimer 

Relevant articles and documents

Electron transfer between mononuclear metal carbonyl anions (M(CO)5-, M = Mn, Re; CpFe(CO)2-; CpM(CO)3-, M = Cr, Mo) and trinuclear clusters (M3(CO)12, M = Fe, Ru, Os) and between trinuclear dianions (M3(CO)112-, M = Fe, Ru, Os) and metal carbonyl dimers (Mn ...

Full title: Electron transfer between mononuclear metal carbonyl anions (M(CO)5-, M = Mn, Re; CpFe(CO)2-; CpM(CO)3-, M = Cr, Mo) and trinuclear clusters (M3(CO)12, M = Fe, Ru, Os) and between trinuclear dianions (M3(CO)112-, M = Fe, Ru, Os) and metal carbonyl dimers (Mn2(CO)10 and Cp2M2(CO)6, M = Cr, Mo, W). Reaction of mononuclear metal carbonyl anions with trinuclear clusters of group 8 (M3(CO)12, M = Fe, Ru, Os) at ambient conditions leads to four separate outcomes: (1) formation of the metal carbonyl dimer and the trinuclear dianion which occurs whenever the two-electron reduction potential for the dimer is more negative than for the trinuclear cluster, (2) formation of MFe2(CO)7- by elimination of Fe(CO)5 which occurs for M = Re(CO)5, Mn(CO)5, and CpMo(CO)3, (3) formation of the adduct, MRu3(CO)11-, which occurs for Re(CO)5, and (4) no reaction when the two-electron reduction potential for the trinuclear complex is more negative than for the dimer. For complexes where the two-electron potential for the cluster is more negative than for the dimer, reaction of M3′(CO)112- with M2 to give M3′(CO)12 and 2M- is observed. The observed reactions allow an estimate of the two-electron reduction potentials for the trinuclear clusters. The kinetics of all of these reactions indicate a first-order dependence on the oxidant and on the reductant and are most consistent with outer-sphere electron transfer.