66051-10-3

Basic information

• Product Name: Cyclohexane, (2-methoxyethenyl)-
• CAS NO: 66051-10-3
• Molecular Formula: C9H16O
• Molecular Weight: 140.225
• Mol File: 66051-10-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexane, (2-methoxyethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, (2-methoxyethenyl)-(66051-10-3)
• EPA Substance Registry System: Cyclohexane, (2-methoxyethenyl)-(66051-10-3)

Safety Data

• Hazardous Substances Data: 66051-10-3(Hazardous Substances Data)

Upstream product

• 14704-14-4 (methoxymethyl)trimethylsilane 
• 2043-61-0 cyclohexanecarbaldehyde 
• 20763-19-3 (methoxymethylene)triphenylphosphorane 
• 95540-70-8 Dithiocarbonic acid O-(1-cyclohexyl-2-methoxy-2-phenylsulfanyl-ethyl) ester S-methyl ester 

Downstream Products

• 140928-41-2 3-ethoxy-3-(trifluoromethyl)-5-cyclohexyl-1,2,4-trioxolane 
• 18869-27-7 (E)-(2-cyclohexylvinyl)benzene 
• 40132-69-2 (Z )-1-(2-cyclohexyl-1-ethenyl)benzene 
• 61153-38-6 (E)-1-(2-cyclohexylvinyl)-4-methylbenzene 
• 4435-14-7 2-cyclohexylacetonitrile 
• 5664-21-1 cyclohexylacetaldehyde 
• 55055-97-5 cyclohexyl αα-dimethoxymethyl cetone 
• 244237-80-7 Cyclohexyl(hydroperoxy)methyl hydroperoxide 
• 4442-79-9 cyclohexylethan-1-ol 
• 139483-03-7 C₁₇H₂₆O₂S 
• 140928-43-4 3-cyclohexyl-5-methoxy-5-(trichloromethyl)-1,2,4-trioxolane 
• 140928-37-6 3-cyclohexyl-5-methoxy-5-(trifluoromethyl)-1,2,4-trioxolane 

Relevant articles and documents

One-Pot Preparation of C1-Homologated Aliphatic Nitriles from Aldehydes through a Wittig Reaction under Metal-Cyanide-Free Conditions

A one-pot protocol to obtain C1-homologated aliphatic nitriles was achieved by treating aromatic and aliphatic aldehydes with the (methoxymethyl)triphenylphosphonium ylide followed by hydrolysis of the resulting methyl vinyl ethers with pTsOH (Ts = para-toluenesulfonyl) and treatment with molecular iodine and aqueous ammonia under metal cyanide free conditions. Neopentyl-type nitriles, which could not be obtained by conventional methods that involved conversion of the neopentyl alcohol into a tosylate and treatment with metal cyanide, were successfully obtained by using the present method.

SYNTHESIS OF VINYL ETHERS BY HOMOLOGATION OF ALDEHYDES VIA RADICAL REDUCTIVE ELIMINATION

Methoxyphenylthiomethyllithium 1 reacts with aldehydes to give adducts which are then transformed into xanthates.These compounds, by reaction with tri-n-butylstannane, afford vinyl ethers in good yields.