66051-39-6

Basic information

• Product Name: 2-Propenoic acid, 2-chloro-3-(4-methoxyphenyl)-, ethyl ester, (E)-
• CAS NO: 66051-39-6
• Molecular Formula: C12H13ClO3
• Molecular Weight: 240.686
• Mol File: 66051-39-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 2-chloro-3-(4-methoxyphenyl)-, ethyl ester, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 2-chloro-3-(4-methoxyphenyl)-, ethyl ester, (E)-(66051-39-6)
• EPA Substance Registry System: 2-Propenoic acid, 2-chloro-3-(4-methoxyphenyl)-, ethyl ester, (E)-(66051-39-6)

Safety Data

• Hazardous Substances Data: 66051-39-6(Hazardous Substances Data)

Upstream product

• 7071-12-7 triethyl 2-chloro-2-phosphonoacetate 
• 123-11-5 4-methoxy-benzaldehyde 
• 5823-12-1 ethyl 2,2-dichloro-2-diethoxyphosphorylacetate 
• 791131-05-0 ethyl chloro(diphenylphosphono)acetate 

Relevant articles and documents

One-pot process in phosphonium-iodonium ylides: Nucleophilic substitution and the Wittig reaction

The nucleophilic substitution in mixed phosphonium-iodonium ylides was investigated. The iodonium group is replaced by such S-containing nucleophiles as the thiocyanate anion or thiourea, as well as by halide ions. The structure of the reaction product with the thiocyanate ion was established by X-ray diffraction. A one-pot process involving the nucleophilic substitution and the Wittig reaction was developed.

Efficient electrosynthesis of α-chloro-α,β-unsaturated carboxylic and phosphonic esters using magnesium electrochemical activation

Various α-chloro-α,β-unsaturated carboxylic or phosphonic esters were easily and rapidly prepared under mild conditions in DMF, by electrolysing respectively triethyl dichloromethylphosphonoacetate and tetraethyl dichloromethyl-bis-phosphonate, then treat