66236-75-7

Basic information

• Product Name: Ethyl, 2-[(1,1-dimethylethyl)thio]-1,1-diphenyl-
• CAS NO: 66236-75-7
• Molecular Formula: C18H21S
• Molecular Weight: 269.431
• Mol File: 66236-75-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethyl, 2-[(1,1-dimethylethyl)thio]-1,1-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethyl, 2-[(1,1-dimethylethyl)thio]-1,1-diphenyl-(66236-75-7)
• EPA Substance Registry System: Ethyl, 2-[(1,1-dimethylethyl)thio]-1,1-diphenyl-(66236-75-7)

Safety Data

• Hazardous Substances Data: 66236-75-7(Hazardous Substances Data)

Upstream product

• 530-48-3 1,1-Diphenylethylene 
• 110-06-5 di-tert-butyl disulfide 

Relevant articles and documents

Reactions of the tert-Butylthiyl Radical with Organometallic Compounds and Alkenes

Absolute rate constants for the reactions of the tert-butylthiyl radical with a variety of substrates were measured by using a combination of laser flash photolysis techniques and product studies.Reactions with organometallic substrates such as boranes, phosphines, and phosphites were extremely rapid with rate constants in the range 1E8 - 1E9 M-1 s-1.By contrast, addition to a simple olefin, oct-1-ene, was ca. 100 times less rapid.However, 1,1-diphenyl- and 1,1-dicyclopropylethylene were remarkably efficient traps for tert-butylthiyl and scavenged the radicalwith rate constants of 9.9*1E8 and 2.4*1E8 M-1 s-1, respectively.