666712-46-5

Basic information

• Product Name: 1-(di-o-tolyl-phosphinothioyl)-pyrrolidine-2-carboxylic acid benzyl ester
• Synonyms: 1-(di-o-tolyl-phosphinothioyl)-pyrrolidine-2-carboxylic acid benzyl ester
• CAS NO: 666712-46-5
• Molecular Weight: 449.554
• Mol File: 666712-46-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(di-o-tolyl-phosphinothioyl)-pyrrolidine-2-carboxylic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(di-o-tolyl-phosphinothioyl)-pyrrolidine-2-carboxylic acid benzyl ester(666712-46-5)
• EPA Substance Registry System: 1-(di-o-tolyl-phosphinothioyl)-pyrrolidine-2-carboxylic acid benzyl ester(666712-46-5)

Safety Data

• Hazardous Substances Data: 666712-46-5(Hazardous Substances Data)

Upstream product

• 36042-94-1 bis(o-tolyl)chlorophosphine 
• 41324-66-7 H-Pro-OBzl 

Downstream Products

• 666723-48-4 (R)-2-{[(S)-1-(Di-o-tolyl-phosphinothioyl)-pyrrolidine-2-carbonyl]-amino}-3,3-dimethyl-butyric acid 
• 666728-96-7 4-tert-butyl-2-[1-(di-o-tolyl-phosphinothioyl)-pyrrolidin-2-yl]-4,5-dihydro-oxazole 
• 666716-75-2 1-(di-o-tolyl-phosphinothioyl)-pyrrolidine-2-carboxylic acid 

Relevant articles and documents

Asymmetric hydrogenation of aromatic olefins catalyzed by iridium complexes of proline derived phosphine-oxazoline ligands

The synthesis of a series of phosphine-oxazoline ligands is reported. This ligands are synthesized by reaction of a phosphine chloride with the secondary nitrogen of proline. Upon coordination to iridium the resulting complexes can be used in the asymmetric hydrogenation of simple olefins. The effect of different counter ions and substitution at the oxazoline and the phosphine is reported.