66675-06-7Relevant articles and documents
Preparation of Formaldehyde and Acetaldehyde Acetals
Barot, Bhalchandra C.,Pinnick, Harold W.
, p. 2981 - 2983 (1981)
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Surface-mediated solid phase reaction. Part 7. A simple and convenient procedure for the methoxymethylation of alcohols with methoxymethyl chloride on the surface of alumina
Ranu,Majee,Das
, p. 363 - 367 (2007/10/02)
A variety of alcohols react with methoxymethyl chloride on the surface of alumina without any solvent to afford the corresponding methoxymethyl ethers in good yields.
Influences on the Selectivity of the Kolbe versus the Non-Kolbe Electrolysis in the Anodic Decarboxylation of Carboxylic Acids
Klocke, Elisabeth,Matzeit, Agnes,Gockeln, Marianne,Schaefer, Hans J.
, p. 1623 - 1630 (2007/10/02)
The anodic decarboxylation of 3-oxanonanoic acid (2a) and 3-oxapentadecanoic acid (2b) in methanol leads exclusively to products of the non-Kolbe electrolysis.The influence of coelectrolysis, solvent, current density, degree of neutralization and chain length of the alkoxy group on the anodic decarboxylation of 2a, b have been investigated.An extended alkyl chain in the alkoxy group, coelectrolysis with long-chain fatty acids, ethanol or dimethylformamide as solvent, and a high current density favor the Kolbe coupling against the non-Kolbe electrolysis.Key Words: Kolbe electrolysis/ Non-Kolbe electrolysis/ Carboxylic acids, α-alkoxy-/ Solvent effects
