6680-06-4

Basic information

• Product Name: olivin
• CAS NO: 6680-06-4
• Molecular Formula: C20H22O9
• Molecular Weight: 406.38328
• Mol File: 6680-06-4.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 722.4°C at 760 mmHg
• Flash Point: 257.7°C
• Appearance: /
• Density: 1.562g/cm³
• Vapor Pressure: 6.61E-22mmHg at 25°C
• Refractive Index: 1.702
• CAS DataBase Reference: olivin(CAS DataBase Reference)
• NIST Chemistry Reference: olivin(6680-06-4)
• EPA Substance Registry System: olivin(6680-06-4)

Safety Data

• Hazardous Substances Data: 6680-06-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C20H22O9/c1-7(21)15(24)19(28)20(29-2)11-5-9-3-8-4-10(22)6-12(23)13(8)17(26)14(9)18(27)16(11)25/h3-4,6-7,11,15-16,20-26H,5H2,1-2H3

Upstream product

• 120264-56-4 (3,5-Bis-benzyloxymethoxy-phenyl)-methanol 
• 111436-89-6 (E)-(4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-5-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-pent-2-enal 
• 111468-56-5 Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--2'-<(carbomethoxymethyl)-4'-<(tert-butyldimethylsilyl)oxy>heptyl>>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate 
• 111436-94-3 Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--2'-(2-oxoethyl)-4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate 
• 111436-92-1 methyl 6,8-bis<(benzyloxy)methoxy>-1-hydroxy-3-<(2'R,3'S,4'R,5'S,6'R)-3'-methoxy-5',6'-(cyclohexylidenedioxy)-4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>naphthoate 
• 111436-90-9 Methyl 5(R),6(S),7(R),8(S),9(R)-6-methoxy-8,9-dihydroxy-7-<(tert-butyldimethylsilyl)oxy>-5-vinyldec-2(E)-enoate 8,9-cyclohexyl ketal 
• 111437-03-7 3(R),4(S),5(R),6(S),7(R)-4-Methoxy-6,7-dihydroxy-5-<(tert-butyldimethylsilyl)oxy>-3-vinyloctanal 6.7-cyclohexyl ketal 
• 2150-44-9 1-carbomethoxy-3,5-dihydroxybenzene 
• 111436-99-8 (2S,3S)-6,8,9-Tris-benzyloxymethoxy-2-(tert-butyl-dimethyl-silanyloxy)-3-[(S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-2-oxo-ethyl]-3,4-dihydro-2H-anthracen-1-one 
• 120264-57-5 (3,5-Bis-benzyloxymethoxy-2-bromo-phenyl)-methanol 
• 120264-55-3 3,5-Bis-benzyloxymethoxy-benzoic acid methyl ester 
• 120264-60-0 6,8,9-Tris-benzyloxymethoxy-3-[(1S,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-ethyl]-1-oxo-1,2,3,4-tetrahydro-anthracene-2-carboxylic acid methyl ester 
• 111437-04-8 Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-2'-<1-(2-hydroxyethyl)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate 
• 111436-93-2 Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate 

Relevant articles and documents

A highly stereoselective synthesis of (+)-olivin, the aglycon of olivomycin A

The first total synthesis of (+)-olivin (1), the naturally occurring enantiomer of the aglycon of olivomycin A, is described. The synthesis is highly stereoselective, featuring the reaction of (γ-methoxyallyl)boronate 21 with chiral aldehyde 17 and the ad

Stereoselective Total Synthesis of the Natural Enantiomer of Olivin Trimethyl Ether

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