6683-49-4

Basic information

• Product Name: 2-Methyl-5-phenyl-1-pentene
• Synonyms: (4-Methyl-4-pentenyl)benzene;2-Methyl-5-phenyl-1-pentene
• CAS NO: 6683-49-4
• Molecular Formula: C₁₂H₁₆
• Molecular Weight: 160.26
• Mol File: 6683-49-4.mol
• Article Data: 12

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Methyl-5-phenyl-1-pentene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Methyl-5-phenyl-1-pentene(6683-49-4)
• EPA Substance Registry System: 2-Methyl-5-phenyl-1-pentene(6683-49-4)

Safety Data

• Hazardous Substances Data: 6683-49-4(Hazardous Substances Data)

Upstream product

• 4830-97-1 1,1-dimethyl-4-phenylbutyl chloride 
• 33324-92-4 (2-methylallyl)magnesium bromide 
• 103-63-9 1-phenyl-2-bromoethane 
• 75553-25-2 (E)-2-Methyl-5-phenyl-2-penten-1-ol 
• 14568-34-4 2-methylprop-2-ene-1-sulfonyl chloride 
• 90878-19-6 phenethylmagnesium chloride 
• 1458-98-6 2-methyl-3-bromo-1-propene 
• 17376-04-4 2-phenethyl iodide 
• 2235-83-8 5-phenyl-2-pentanone 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 119405-97-9 4-phenyl-1,1-dibromo-1-butene 
• 104-53-0 3-phenyl-propionaldehyde 
• 683773-81-1 1,1-bis[(trimethylsilyl)methyl]-4-phenyl-1-pentene 
• 1823-14-9 5-phenyl-1-pentyne 

Downstream Products

• 31444-36-7 2-methyl-1,5-diphenylpentane 
• 38899-53-5 1-Benzyl-1-methyl-tetralin 
• 57497-02-6 1-Brom-2-methyl-5-phenyl-1-penten 
• 123718-22-9 (+/-)-2-methyl-5-phenylpent-1-en-3-ol 
• 39520-67-7 2-hydroxymethyl-5-phenyl-1-pentene 
• 25634-93-9 2-methyl-5-phenyl pentanol 
• 69815-01-6 4-methyl-1-phenylpentane-1,4-diol 
• 41635-77-2 hexa-1,3-dien-1-ylbenzene 
• 57497-03-7 1-methyl-3-phenyl-1-cyclopentene 
• 57497-04-8 3-Methyl-1-phenylcyclopent-1-ene 
• 34298-75-4 hex-4-yn-1-ylbenzene 

Relevant articles and documents

Palladium-Catalyzed Electrochemical Allylic Alkylation between Alkyl and Allylic Halides in Aqueous Solution

A new route for the direct cross-coupling of alkyl and allylic halides using electrochemical technique has been developed in aqueous media under air. Catalyzed by Pd(OAc)2, the Zn-mediated allylic alkylations proceed smoothly between a full range of alkyl halides (primary, secondary, and tertiary) and substituted allylic halides. Protection-deprotection of acidic hydrogen in the substrates is avoided.

Palladium-catalyzed desulfinylative C-C allylation of Grignard reagents and enolates using allylsulfonyl chlorides and esters

2-Methylprop-2-ene-, prop-2-ene-, 1-methylprop-2-ene-, and (E)-but-2-enesulfonyl chlorides have been used as electrophilic partners in desulfinylative palladium-catalyzed C-C coupling with Grignard reagents and sodium salts of dimethyl malonate and methyl

Preparation of 2-trimethylsilylmethyl-1-alkene; cross-coupling and protodesilylation sequence from 1,1-dibromo-1-alkene

A new method for the preparation of exomethylene type allylsilane is described. Selective mono-protodesilylation of 1-trimethylsilyl-2-trimethylsilylmethyl-2-alkenes 2 with PPTS afforded 2-trimethylsilylmethyl-1-alkenes 4 in excellent yields. Since the resulting allylsilanes 4 possess an exomethylene unit, the reactions of 4 with carbonyl compounds in the presence of Lewis acids gave the corresponding product 7 having an exomethylene unit in excellent yields.