67276-04-4

Basic information

• Product Name: SODIUM TRI-SEC-BUTYLBOROHYDRIDE
• Synonyms: n-selectride;sodiumtri-sec-butylborohydride,calselect?na,;sodiumtri-sec-butylborohydride,calselect?na,intetrahydrofuran;SODIUM TRI-SEC-BUTYLBOROHYDRIDE;N-SELECTRIDE(R);sodium hydrotri-sec-butylborate(1-);Sodium tri-sec-butylborohydride, in tetrahydrofuran;N-SELECTRIDE, 1.0M SOLUTION IN TETRAHYDR OFURAN
• CAS NO: 67276-04-4
• Molecular Formula: C₁₂H₂₈B*Na
• Molecular Weight: 206.15
• EINECS: 266-630-5
• Mol File: 67276-04-4.mol
• Article Data: 4

Chemical Properties

• Flash Point: 5 °F
• Appearance: /
• Density: 0.893 g/mL at 25 °C(lit.)
• Storage Temp.: Flammables + water-Freezer (-20°C)e area
• CAS DataBase Reference: SODIUM TRI-SEC-BUTYLBOROHYDRIDE(CAS DataBase Reference)
• NIST Chemistry Reference: SODIUM TRI-SEC-BUTYLBOROHYDRIDE(67276-04-4)
• EPA Substance Registry System: SODIUM TRI-SEC-BUTYLBOROHYDRIDE(67276-04-4)

Safety Data

• Hazard Codes: F,C
• Statements: 11-14/15-19-22-34-37-40
• Safety Statements: 16-26-27-36/37/39-45-43
• RIDADR: UN 3399 4.3/PG 1
• WGK Germany: 1
• Hazardous Substances Data: 67276-04-4(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 67276-04-4 differently. You can refer to the following data:
1. Reducing agent Reactant for: Conjugate hydride reduction-initiated tandem cyclization reactions Sereoselective nucleophilic addition reactions.
2. Reducing agentReactant for:Conjugate hydride reduction-initiated tandem cyclization reactionsSereoselective nucleophilic addition reactions

InChI:InChI=1/C12H27B.Na/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-12H,7-9H2,1-6H3;/q-1;+1

Upstream product

• 1113-78-6 tri(sec-butyl)borane 
• 1333-74-0 hydrogen 
• 7440-23-5 sodium 

Downstream Products

• 14984-74-8 difluorophosphine 
• 7803-51-2 phosphan 
• 7783-55-3 trifluorophosphane 
• 1113-78-6 tri(sec-butyl)borane 

Relevant articles and documents

Reaction of Trialkylboranes with Sodium Diethylhydroaluminate in the Presence of 1,4-Diazabicylooctane: a Convenient, General Method for Preparation of Sodium Trialkylhydroborates

Trialkylboranes in tetrahydrofuran solution, even those with exceptionally large steric requirements, react readily with toluene solutions of sodium diethyldihydroaluminate in the presence of 1,4-diazabicyclooctane, resulting in a convenient and general preparation of sodium trialkylhydroborates.

Method for producing alkali metal monohydridoborates and monohydridoaluminates

The invention relates to a method for producing compounds of general formula (A) by reacting an alkali metal hydride with a compound (B) during which the reaction is carried out in the presence of a catalyst that contains boron, whereby: M represents Li, Na, K, Rb or Cs; E represents B or Al, and; X1, X2, X3, independent of one another, represent a secondary or tertiary alkyl group, which is comprised of 2 to 10 atoms, or represent a phenyl group which itself can be alkyl-substituted or they represent an alkoxy group, and the catalyst, which contains boron, or the conversion product thereof with MH is capable of acting as a hydride transfer agent.