67459-71-6

Basic information

• Product Name: potassium diisopropyl amide
• Synonyms: potassium diisopropyl amide
• CAS NO: 67459-71-6
• Molecular Weight: 139.282
• Mol File: 67459-71-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: potassium diisopropyl amide(CAS DataBase Reference)
• NIST Chemistry Reference: potassium diisopropyl amide(67459-71-6)
• EPA Substance Registry System: potassium diisopropyl amide(67459-71-6)

Safety Data

• Hazardous Substances Data: 67459-71-6(Hazardous Substances Data)

Upstream product

• 108-18-9 diisopropylamine 
• 110426-36-3 KCH₂C₆H₃Me₂ 
• 2678-95-7 C₈H₉K 
• 55301-50-3 C₈H₉K 
• 55301-52-5 p-methylbenzylpotassium 
• 2785-29-7 benzyl potassium 
• 128291-28-1 2'-isopropenylpotassium 

Downstream Products

• 108-18-9 diisopropylamine 
• 2785-29-7 benzyl potassium 
• 128291-28-1 2'-isopropenylpotassium 
• 110426-36-3 KCH₂C₆H₃Me₂ 
• 2678-95-7 C₈H₉K 
• 55301-52-5 p-methylbenzylpotassium 
• 55301-50-3 C₈H₉K 

Relevant articles and documents

ON THE DIRECT METALATION OF ISOPRENE

Isoprene has been metalated in tetrahydrofuran with an excess of sterically hindered potassium dialkylamides, prepared by combining equimolar amounts of the corresponding lithium amide and potassium tert-butoxide.Subsequent reaction with oxirane, alkyl bromides, and pivaldehyde gave the expected coupling products in reasonable yields.Coupling with (CH3)2CHCH2CH=O and (CH3)2C=CHCH=O afforded the bark beetle pheromones (+/-)-ipsenol and (+/-)-ipsdienol in low yields.