67462-22-0

Basic information

• Product Name: L-MENTHYL-A-D-GLUCOPYRANOSIDE N-HYDRATE
• Synonyms: L-MENTHYL-A-D-GLUCOPYRANOSIDE N-HYDRATE
• CAS NO: 67462-22-0
• Molecular Formula: C₁₆H₃₀O₆
• Molecular Weight: 336.42
• Mol File: 67462-22-0.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: L-MENTHYL-A-D-GLUCOPYRANOSIDE N-HYDRATE(CAS DataBase Reference)
• NIST Chemistry Reference: L-MENTHYL-A-D-GLUCOPYRANOSIDE N-HYDRATE(67462-22-0)
• EPA Substance Registry System: L-MENTHYL-A-D-GLUCOPYRANOSIDE N-HYDRATE(67462-22-0)

Safety Data

• Hazardous Substances Data: 67462-22-0(Hazardous Substances Data)

Upstream product

• 16203-27-3 (-)-menthyl β-D-glucopyranoside 
• 15356-70-4 menthol 
• 2216-51-5 (-)-menthol 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 

Downstream Products

• 19464-71-2 O¹-((1R)-menthyl)-α-D-glucopyranuronic acid 

Relevant articles and documents

Enantioselective glucosylation of (±)-secondary alcohols with plant glucosyltransferases

Two glucosyltransferases were isolated from plant cell cultures of Catharanthus roseus and Nicotiana tabacum. The enzyme from C. roseus enantioselectively glucosylated (±)-secondary alcohols to give the glucosides of (R)-alcohols, while the glucosylation with that from N. tabacum gave preferentially the glucosides of (S)-alcohols.

Anomer selective formation of l-menthyl α-D-glucopyranoside by α- glucosidase-catalyzed reaction

l-Menthol was glucosylated by the α-glucosidase (EC 3.2.1.20) of Saccharomyces cerevisiae using maltose as glucosyl donor. When 50 mg of l- menthol and 1 M maltose in 10 mM citrate-phosphate buffer (pH 7.0) were incubated for 24 h at 30°C, a menthylglucoside was selectively obtained as a product. The molar conversion yield based on supplied menthol was 4.5%. The product was identified as l-menthyl α-D-glucopyranoside (α-MenG) by 13C- NMR analysis.