67681-66-7Relevant articles and documents
A method for the preparation of allyl silane (by machine translation)
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Paragraph 0030-0033; 0038-0039, (2017/08/31)
The invention provides a method for the preparation of allyl silane, propyl silane of the general formula structure dimerizes as formula (I) as shown; wherein R, R 'and R is the same or different, to keep at least a hydrolisis active group, R, R' and R are independently selected from alkoxy, halogen, alkyl, unsaturated alkyl or aryl group; comprises the following steps: S1, in under the nitrogen atmosphere, will R1 R2 R3 SiR4 , Splicing, the catalyst mixing, heating; S2, in S1 in the mixed solution of first add a certain amount of halogen propylene reaction; S3, the S2 at the reflux temperature of the reactant in the reaction 4 - 6 hours; S4, adding excess halogen propylene, continue to reaction, thermal insulation 30 - 50 minutes; after the completion of the reaction, filtration, purification, to get the dimerizes propyl silane. The present invention provides a preparation method does not need of flammable solvent to participate in the reaction, to avoid production of dangerous, greatly simplifies the process steps and reduce the cost, the production cost of the lowest synthesis in the product, at the same time facile product, the reaction yield is high. (by machine translation)