682-11-1Relevant articles and documents
Selective functionalization of the primary hydroxy group in triols
Raskil'Dina,Valiev,Sultanova,Zlotskii
, p. 1599 - 1604 (2016/02/18)
A procedure was suggested for preparing functionally substituted 1,2-diols by O-alkylation of hydroxyalkyl-1,3-dioxacyclanes with alkyl halides, followed by acid hydrolysis. The conditions for selective cleavage of the ethers obtained were found. (2,2-Dimethyl-1,3-dioxolan-4-yl)methyl benzoate under the conditions of acid deacetalization undergoes saponification of the ester group.