68294-33-7

Basic information

• Product Name: (4'-METHOXYBIPHENYL-4-YL)-PHENYL-METHANONE
• Synonyms: (4'-METHOXYBIPHENYL-4-YL)-PHENYL-METHANONE;Benzophenone, 4-(p-methoxyphenyl)- (6CI,7CI);4-Benzoyl-4'-methoxy-1,1'-biphenyl;p-(4-Methoxyphenyl)benzophenone
• CAS NO: 68294-33-7
• Molecular Formula: C₂₀H₁₆O₂
• Molecular Weight: 288.34
• Mol File: 68294-33-7.mol
• Article Data: 20

Chemical Properties

• Melting Point: 167-168℃
• Boiling Point: 451 °C at 760 mmHg
• Flash Point: 198.9 °C
• Appearance: /
• Density: 1.122 g/cm³
• CAS DataBase Reference: (4'-METHOXYBIPHENYL-4-YL)-PHENYL-METHANONE(CAS DataBase Reference)
• NIST Chemistry Reference: (4'-METHOXYBIPHENYL-4-YL)-PHENYL-METHANONE(68294-33-7)
• EPA Substance Registry System: (4'-METHOXYBIPHENYL-4-YL)-PHENYL-METHANONE(68294-33-7)

Safety Data

• Hazardous Substances Data: 68294-33-7(Hazardous Substances Data)

Usage

General Description

(4'-Methoxybiphenyl-4-yl)-phenyl-methanone is a chemical compound with a molecular formula C20H16O2. It is a ketone derivative with a biphenyl structure and a methoxy group attached to one of the phenyl rings. (4'-Methoxybiphenyl-4-yl)-phenyl-methanone is used in organic synthesis and pharmaceutical research as a building block for the synthesis of other compounds. It has potential applications in the development of new drugs and materials. Additionally, it may also have uses in various chemical reactions and industrial processes. However, further research and testing are needed to fully understand its properties and potential uses.

Upstream product

• 119-61-9 benzophenone 
• 725-14-4 4'-methoxy-biphenyl-4-carboxylic acid 
• 5623-46-1 4-(4'-hydroxyphenyl)benzophenone 
• 77-78-1 dimethyl sulfate 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 90-90-4 (4-bromophenyl)(phenyl)methanone 
• 5720-07-0 4-methoxyphenylboronic acid 
• 124643-34-1 p-benzoylphenyl triflate 
• 345-83-5 4-fluorobenzophenone 
• 93296-09-4 4-methoxyphenylzinc chloride 
• 1159803-53-8 2-(4-methoxyphenyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]-diazaborinine 
• 623-12-1 4-chloromethoxybenzene 
• 269410-03-9 phenyl-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methanone 
• 134-85-0 4-chlorobenzophenone 

Downstream Products

• 63242-26-2 4-methoxy-4'-(α-hydroxybenzyl)biphenyl 
• 622407-99-2 4-(4'-methoxyphenyl)-α-methylbenzhydrol 
• 5623-46-1 4-(4'-hydroxyphenyl)benzophenone 
• 63242-38-6 4-(4-Methoxyphenyl)-diphenylmethylchlorid 
• 861096-89-1 4'-(hydroxydiphenylmethyl)biphenyl-4-ol 
• 622408-01-9 4'-(4''-methoxyphenyl)-1,1-diphenylethylene 
• 622408-03-1 4-hydroxy-4'-(α-hydroxybenzyl)biphenyl 
• 913369-62-7 C₆H₅CHC₆H₄C₆H₄O 
• 95742-90-8 1-benzyl-4-(4-methoxyphenyl)benzene 
• 861097-26-9 (4'-methoxybiphenyl-4-yl)diphenylmethanol 

Relevant articles and documents

Mechanochemical Solvent-Free Suzuki–Miyaura Cross-Coupling of Amides via Highly Chemoselective N?C Cleavage

Although cross-coupling reactions of amides by selective N?C cleavage are one of the most powerful and burgeoning areas in organic synthesis due to the ubiquity of amide bonds, the development of mechanochemical, solid-state methods remains a major challe

Direct suzuki-miyaura coupling with naphthalene-1,8-diaminato (dan)-substituted organoborons

The actually direct Suzuki-Miyaura coupling with "protected" R-B(dan) (dan = naphthalene-1,8-diaminato) was demonstrated to smoothly occur without in situ deprotection of the B(dan) moiety. The use of t-BuOK (Ba(OH)2 in some cases) as a base under anhydrous conditions is the key to the successful cross-coupling, where R-B(dan) is readily converted into a transmetalation-active borate-form, regardless of the well-accepted diminished boron-Lewis acidity.

Cross-Coupling of Aryl Trifluoromethyl Sulfones with Arylboronates by Cooperative Palladium/Rhodium Catalysis

The Suzuki-Miyaura arylation of aryl trifluoromethyl sulfones via C-SO2 bond cleavage has been developed by means of cooperative palladium/rhodium catalysis. A series of aryl trifluoromethyl sulfones and arylboronic acid neopentylglycol esters are converted to the corresponding biaryls. Mechanistic investigations suggest that (1) the rhodium catalyst mediates the transfer of the aryl ring from arylboronate to palladium, resulting in the acceleration of the transmetalation step, and (2) the C-C bond-forming reductive elimination step is the turnover-limiting step.