6838-67-1

Basic information

• Product Name: 1,2-Bis(trimethylsilyloxy)cyclohexene
• Synonyms: 1,2-Bis(trimethylsilyloxy)cyclohexene;1,2-Bis[(trimethylsilyl)oxy]cyclohexene
• CAS NO: 6838-67-1
• Molecular Formula: C₁₂H₂₆O₂Si₂
• Molecular Weight: 258.5
• Mol File: 6838-67-1.mol
• Article Data: 16

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,2-Bis(trimethylsilyloxy)cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Bis(trimethylsilyloxy)cyclohexene(6838-67-1)
• EPA Substance Registry System: 1,2-Bis(trimethylsilyloxy)cyclohexene(6838-67-1)

Safety Data

• Hazardous Substances Data: 6838-67-1(Hazardous Substances Data)

Usage

Chemical structure

A cyclohexene ring with two trimethylsilyloxy (TMS) groups attached to the 1 and 2 positions.

Functional groups

Contains a cyclohexene ring and two TMS groups.

Role in organic chemistry

Commonly used as a synthetic intermediate in organic chemistry reactions.

Protection and stability

The TMS groups provide stability and protection to reactive functional groups during chemical transformations.

Applications

Utilized in the production of pharmaceuticals, agrochemicals, and other specialty chemicals.

Versatile reactivity

Exhibits versatile reactivity in various synthetic pathways, making it a valuable compound for chemical synthesis.

Research utility

A valuable tool for researchers in the field of organic chemistry for the construction of complex molecules.

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 13482-22-9 4-hydroxycyclohexanone 
• 18306-29-1 bis(trimethylsilyl)sulphate 
• 765-87-7 cyclohexane-1,2-dione 
• 141-28-6 diethyl adipate 
• 627-93-0 hexanedioic acid dimethyl ester 

Downstream Products

• 60278-05-9 1-hydroxy-[1,1'-bi(cyclohexan)]-2-one 
• 60277-93-2 2-ethyl-2-hydroxycyclohexan-1-one 
• 60278-02-6 2-n-Hexyl-2-hydroxy-cyclohexanon 
• 60277-96-5 2-allyl-2-hydroxycyclohexanone 
• 16117-23-0 6,6,13,13-tetraphenyl-1,2,3,4,8,9,10,11-octahydro-dibenzo[d,i][1,3,6,8,2,7]tetroxadisilecine 
• 1468-24-2 cyclohexane-1,2-dione-bis-(2,4-dinitro-phenylhydrazone) 
• 88264-40-8 2-(1-Adamantyl)-2-hydroxy-1-cyclohexanon 
• 75-77-4 chloro-trimethyl-silane 
• 83092-09-5 2-Butoxy-4,5,6,7-tetrahydro-benzo[1,3,2]dioxaphosphole 
• 79425-68-6 Diethyl-(4,5,6,7-tetrahydro-benzo[1,3,2]dioxaphosphol-2-yl)-amine 
• 344441-67-4 2-Hydroxy-2-(1,2,3,4-tetrahydro-1-naphthyl)-1-cyclohexanon 
• 78743-57-4 2-hydroxy-2-methoxymethylcyclohexanone 
• 942-01-8 1,2,3,4-tetrahydrocarbazole 

Relevant articles and documents

Green synthesis method for 1,2-bi(trialkyl siloxy) cyclohexene

The invention relates to a green synthesis method for 1,2-bi(trialkyl siloxy) cyclohexene. The method comprises the step of causing 1,2-cyclohexanone, bi(trialkyl silicon) sulphate and reactive metalreact in an inert solvent, thereby acquiring 1,2-bi(trialkyl siloxy) cyclohexene. The bi(trialkyl silicon) sulphate is prepared according to the steps of preparing hexalkyl disiloxane by dehydrating by-product trialkyl silanol in consequent reaction and then continuing to react with concentrated sulfuric acid. The environmental issue of siloxane effluent is completely solved through the recyclingof silicon protecting group; the produced solid waste has a single component and can be prepared into byproduct for sale after simple treatment; the emission of three wastes is less; the technology isenvironment-friendly.

Chemoselective activation of trimethylsilyl enol ether functionalities in the presence of silyl-protected alcohols by trimethylsilyl-nonaflyl exchange

Trimethylsilyl enol ethers bearing trialkylsilyl-protected hydroxy groups were converted into synthetically valuable bifunctional alkenyl nonaflates under the action of nonafluorobutane-1-sulfonyl fluoride combined with potassium fluoride in the presence

Fancy bioisosteres: Synthesis and dopaminergic properties of the endiyne FAUC 88 as a novel non-aromatic D3 agonist

Enlargement of the π-electronic system of the non-aromatic D3 agonist FAUC 73 led to dopaminergic endiynes of type 1 being synthesized via the bromovinyl triflate 7a as a key intermediate when palladium catalyzed coupling reactions were exploited for the