68409-04-1Relevant articles and documents
ELECTROCHEMICAL INITIATION OF THE RADICAL-ION REACTIONS OF PERFLUOROALKYL HALIDES II. ELECTROCHEMICAL SYNTHESIS OF ARYL AND ALKYL POLYFLUOROALKYL SULFIDES
Ignat'ev, N. V.,Datsenko, S. D.,Yagupol'skii, L. M.
, p. 780 - 784 (2007/10/02)
An electrochemical method was developed for the synthesis of aryl and alkyl polyfluoroalkyl sulfides based on the electrochemical initiation of the radical-ion chain reaction of thiolate ions with perfluoro- and polyfluoroalkyl iodides and bromides.
Free-Radical Reactions of Fluoroalkanesulfenyl Halides. 4. Reactions of Perfluoroalkane- and Pentafluorobenzenesulfenyl Chlorides with Hydrocarbons in the Presence of Fluorinated Disulfides
Harris, J. F.
, p. 268 - 271 (2007/10/02)
Free-radical reactions of perfluoroalkanesulfenyl chlorides and pentafluorobenzenesulfenyl chloride with cyclohexane and toluene were carried out in the presence of bis(perfluoroalkyl) disulfides and bis(pentaflurophenyl)disulfide to assess the competition between the disulfide and the sulfenyl chloride for reaction with hydrocarbon radicals.With added bis(perfluoroalkyl) disulfides, radical attack occurs only on the sulfenyl chloride, but with added bis(pentafluorophenyl) disulfide, attack occurs on both sulfenyl chloride and disulfide.