68661-19-8Relevant articles and documents
Studies on drug metabolism by use of isotopes. XXIV. Determination of 3-phenylpropyl carbamate metabolites using stable isotope labelling with deuterium or carbon-13
Horie,Baba
, p. 63 - 66,64, 65 (1979)
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Experimental and Theoretical Studies on Gas-Phase Fragmentation Reactions of Protonated Methyl Benzoate: Concomitant Neutral Eliminations of Benzene, Carbon Dioxide, and Methanol
Xia, Hanxue,Zhang, Yong,Attygalle, Athula B.
, p. 1601 - 1610 (2018/07/29)
Protonated methyl benzoate, upon activation, fragments by three distinct pathways. The m/z 137 ion for the protonated species generated by helium-plasma ionization (HePI) was mass-selected and subjected to collisional activation. In one fragmentation path
Efficient and selective Pt/C-catalyzed H-D exchange reaction of aromatic rings
Ito, Nobuhiro,Esaki, Hiroyoshi,Maesawa, Tsuneaki,Imamiya, Eikoh,Maegawa, Tomohiro,Sajiki, Hironao
experimental part, p. 278 - 286 (2009/03/12)
An effective and applicable deuteration method for aromatic rings using Pt/C-D2O-H2 system was established. Especially, phenol was fully deuterated even at room temperature, and other electron-rich aromatic nuclei were efficiently deuterated under mild conditions. The scope and limitations of the presence method and its application to the synthesis of deuterium-labeled biologically active compounds and deuterium-labeled building blocks for practical multi-gram scale syntheses are reported. 2008 The Chemical Society of Japan.
