6909-13-3

Basic information

• Product Name: trans N,N-dimethylamino-2 trans p-menthanol
• Synonyms: trans N,N-dimethylamino-2 trans p-menthanol
• CAS NO: 6909-13-3
• Molecular Weight: 199.337
• Mol File: 6909-13-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans N,N-dimethylamino-2 trans p-menthanol(CAS DataBase Reference)
• NIST Chemistry Reference: trans N,N-dimethylamino-2 trans p-menthanol(6909-13-3)
• EPA Substance Registry System: trans N,N-dimethylamino-2 trans p-menthanol(6909-13-3)

Safety Data

• Hazardous Substances Data: 6909-13-3(Hazardous Substances Data)

Upstream product

• 78478-85-0 (1S,2S,4R)-2-(dimethylamino)-1-methyl-4-(1-methylethenyl)cyclohexanol 

Downstream Products

• 117556-62-4 (1S,4S)-4-isopropyl-1-methyl-2-cyclohexen-1-ol 

Relevant articles and documents

Hydrogenation en phase liquide sur Pd/C de derives mono et disubstitues du limonene

Various derivatives of limonene, either monosubstituted: cis and trans-β-terpineols, (+) neodihydrocarveol, (-) isopulegol, or disubstituted: (+)-trans-N,N-2-dimethylamino-8-trans-p-menthene-1-ol, (+)-N,N-1-dimethylaminoneodihydrocarveol and (+)-trans-N,N-2-dimethylamino-8-cis-p-menthene-1-ol, have been hydrogenated on Pd/C or Adams PtO2 at 25 deg C and under a pressure of 1 atm in ether.With PtO2 the only product obtained has the same configuration as the starting material.On the opposite, due to its isomerising character, Pd/C leads to a mixture of two stereoisomers by racemisation of the asymmetric carbon at position 4 through migration of the exocyclic isopropenyl double bond.In the case of (+) neohydrocarvomenthone (4R) the double bond enters the ring, and so (+) carvomenthone (4R) and (-) isocarvomenthone (4S) are obtained.