69392-27-4Relevant articles and documents
Development of enantioselective synthetic routes to (-)-Kinamycin F and (-)-lomaiviticin aglycon
Woo, Christina M.,Gholap, Shivajirao L.,Lu, Liang,Kaneko, Miho,Li, Zhenwu,Ravikumar, P. C.,Herzon, Seth B.
, p. 17262 - 17273,12 (2020/09/02)
The development of enantioselective synthetic routes to (-)-kinamycin F (9) and (-)-lomaiviticin aglycon (6) are described. The diazotetrahydrobenzo[b] fluorene (diazofluorene) functional group of the targets was prepared by fluoride-mediated coupling of
MOLYBDENUM CATALYZED ELIMINATIONS OF ALLYLIC ACETATES. NEW DIENE SYNTHESIS
Trost, Barry M.,Lautens, Mark,Peterson, Brian
, p. 4525 - 4528 (2007/10/02)
Allyl acetates smoothly eliminate the elements of acetic acid in the presence of O,N-bis(trimethylsilyl)acetamide and molybdenum hexacarbonyl; a simple sequence permits elaboration of saturated aldehydes into α,β,γ,δ-dienoates which resulted in a four step synthesis of trichonine.