69739-32-8

Basic information

• Product Name: 4-Thiazolidinecarboxylic acid, 2-phenyl-, methyl ester, (2S,4R)-
• CAS NO: 69739-32-8
• Molecular Formula: C11H13NO2S
• Molecular Weight: 223.296
• Mol File: 69739-32-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 4-Thiazolidinecarboxylic acid, 2-phenyl-, methyl ester, (2S,4R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Thiazolidinecarboxylic acid, 2-phenyl-, methyl ester, (2S,4R)-(69739-32-8)
• EPA Substance Registry System: 4-Thiazolidinecarboxylic acid, 2-phenyl-, methyl ester, (2S,4R)-(69739-32-8)

Safety Data

• Hazardous Substances Data: 69739-32-8(Hazardous Substances Data)

Upstream product

• 18598-63-5 L-cysteine methyl ester hydrochloride 
• 100-52-7 benzaldehyde 
• 5714-80-7 D-cysteine methyl ester hydrochloride 

Relevant articles and documents

Viable use of 2-substituted thiazolidine-4-methanol diastereoisomeric mixtures during asymmetric borane reduction of aromatic ketones

The reduction of aromatic ketones by borane in the presence of the inseparable diastereoisomeric mixture of 2-substituted thiazolidine-4- methanol has been investigated. Modest to high enantiomeric excesses were obtained increasing with thiazolidine steri

Chemoselectivity and stereoselectivity of cyclisation pathways leading to bicyclic tetramates controlled by ring-chain tautomerisation in thiazolidines

Chemoselective Dieckmann cyclisation reactions on N-malonyl thiazolidine templates derived from cysteine and pivaldehyde or aromatic aldehydes may be used to access bicyclic tetramates, for which different pathways operate as a result of differing ring-chain tautomeric behaviour of the respective intermediate imines.

Modular chiral thiazolidine catalysts in asymmetric aryl transfer reactions

Modular chiral thiazolidine derivatives were synthesized in a single step from inexpensive and commercially available starting materials. These ligands catalyzed enantioselective arylation of different aldehydes using aryl boronic acids as a source of transferable aryl groups. The products were obtained in excellent yields and good enantioselectivities.