69754-58-1

Basic information

• Product Name: (hydroxy-1 cyclohexyl)-3 octadiene-1,2
• Synonyms: (hydroxy-1 cyclohexyl)-3 octadiene-1,2
• CAS NO: 69754-58-1
• Molecular Weight: 208.344
• Mol File: 69754-58-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (hydroxy-1 cyclohexyl)-3 octadiene-1,2(CAS DataBase Reference)
• NIST Chemistry Reference: (hydroxy-1 cyclohexyl)-3 octadiene-1,2(69754-58-1)
• EPA Substance Registry System: (hydroxy-1 cyclohexyl)-3 octadiene-1,2(69754-58-1)

Safety Data

• Hazardous Substances Data: 69754-58-1(Hazardous Substances Data)

Upstream product

• 54369-44-7 methanesulfonic acid oct-2-ynyl ester 
• 20739-58-6 2-octyn-1-ol 
• 111847-83-7 3-(trimethylstannyl)-1,2-octadiene 
• 108-94-1 cyclohexanone 
• 18495-27-7 1-bromooct-2-yne 

Relevant articles and documents

SYNTHESE D'ALCOHOLS α-ALLENIQUES PAR REACTION D'ORGANOCHROMIQUES PROPARGYLIQUES SUR LES ALDEHYDES ET LES CETONES

Propargylic bromides can be condensed with aldehydes and ketones in the presence of Hiyama's reagent (2CrCl3+LiAlH4 in THF) leading to α-allenic alcohols, to homopropargylic alcohols or to the mixture of both of them.The selectivity (or specificity) of this reaction depends on the substitution of the propargylic bromide, on the structure of the ketone, and on the presence of HMPT in the reaction mixture.In many cases, α- allenic alcohol has been specifically or very selectively obtained.The mechanism of the reaction and the influence of the various parameters are discussed.