69767-96-0

Basic information

• Product Name: 1H-Imidazole-2-carboxaldehyde,1-ethenyl-(9CI)
• Synonyms: 1H-Imidazole-2-carboxaldehyde,1-ethenyl-(9CI);1-vinyl-1H-imidazole-2-carbaldehyde
• CAS NO: 69767-96-0
• Molecular Formula: C₆H₆N₂O
• Molecular Weight: 122.126
• Product Categories: AMINETERTIARY
• Mol File: 69767-96-0.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 281.3±23.0 °C(Predicted)
• Appearance: /
• Density: 1.08±0.1 g/cm3(Predicted)
• PKA: 1.29±0.69(Predicted)
• CAS DataBase Reference: 1H-Imidazole-2-carboxaldehyde,1-ethenyl-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Imidazole-2-carboxaldehyde,1-ethenyl-(9CI)(69767-96-0)
• EPA Substance Registry System: 1H-Imidazole-2-carboxaldehyde,1-ethenyl-(9CI)(69767-96-0)

Safety Data

• Hazardous Substances Data: 69767-96-0(Hazardous Substances Data)

Usage

Type of compound

heterocyclic aldehyde
It is classified as a heterocyclic aldehyde because it contains a heterocyclic ring (imidazole) with an aldehyde functional group.

Imidazole derivative

yes
1H-Imidazole-2-carboxaldehyde,1-ethenyl-(9CI) is a derivative of imidazole, which means it is a modified version of the imidazole structure.

Structural features

vinyl group attached to the imidazole ring
A vinyl group (an ethene unit) is attached to the imidazole ring, making it 1-ethenyl-1H-imidazole-2-carboxaldehyde.

Usage in chemical synthesis

yes
This compound may be used in various chemical synthesis processes, such as in the preparation of pharmaceuticals or other organic compounds.

Specific properties and potential uses

context-dependent
The specific properties and potential uses of 1H-Imidazole-2-carboxaldehyde,1-ethenyl-(9CI) will depend on the context and the specific applications for which it is being used.

Upstream product

• 45662-46-2 1-vinyl-2-hydroxymethylimidazole 
• 215512-69-9 1-vinylimidazol-2-ylmethanediol 
• 1072-63-5 1-vinylimidazole 
• 109-94-4 formic acid ethyl ester 
• 68-12-2 N,N-dimethyl-formamide 

Downstream Products

• 475475-53-7 2-[(diphenylphosphinoyl)hydroxymethyl]-1-vinylimidazole 
• 548463-14-5 2-(1-vinylimidazol-2-yl)methyleneaminopyridine 
• 548463-10-1 3-(1-vinylimidazol-2-yl)methyleneaminopyridine 
• 902138-02-7 2-[bis(2-phenylethyl)thiophosphorylhydroxymethyl]-1-vinylimidazole 

Relevant articles and documents

Specific intramolecular C-H...O interactions in 1-vinyl-2-formylimidazole and 1-vinyl-2-formylbenzimidazole studied by 1H and 13C NMR spectral data

According to the 1H and 13C NMR spectral data, the vinyl group in 1-vinyl-2-formylimidazole and 1-vinyl-2-formylbenzimidazole is trans-oriented with respect to the formyl fragment, while the carbonyl group occupies the anti-position with respect to the N atom of pyridine cycle. A specific intramolecular C-H...O interaction of a weak hydrogen bond type is realized between the α-H atom of the vinyl group and O atom of the carbonyl group.

Enhanced hydrolytic activity of Cu(II) and Zn(II) complexes in highly cross-linked polymers

The chelate ligand tris[(1-vinylimidazol-2-yl)methyl]amine (5) was synthesized in five steps from commercially available starting materials. Upon reaction with ZnCl2 or CuCl2 in the presence of NH 4PF6, the complexes [Zn(5)Cl]PF6 (6) and [Cu(5)Cl]PF6 (7) were obtained. The structure of both complexes was determined by single-crystal X-ray crystallography. Immobilization of 6 and 7 was achieved by co-polymerization with ethylene glycol dimethacrylate. The supported complexes P6-Zn and P7-Cu were found to be efficient catalysts for the hydrolysis of bis(p-nitrophenyl)phosphate (BNPP) at 50 °C. At pH 9.5, the heterogeneous catalyst P7-Cu was 56 times more active than the homogeneous catalyst 7. Partitioning effects, which increase the local concentration of BNPP in the polymer, are shown to contribute to the enhanced activity of the immobilized catalyst. The Royal Society of Chemistry 2006.

6-beta(substituted)-(S)-hydroxymethylpenicillanic acids and derivatives thereof

Antibacterial penicillins of the formula STR1 or a pharmaceutically acceptable salt thereof wherein R1 is a heterocyclic group and R is hydrogen, the residue of certian carboxy protecting groups or the residue of an ester group readily hydrolyzable in vivo having activity against resistant organisms.